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79417

Phosphazen-Base P2-Et

≥98.0% (NT)

Synonym(e):

1-Ethyl-2,2,4,4,4-pentakis-(dimethylamino)-2λ5,4λ5-catenadi-(phosphazen), Tetramethyl-(tris-(dimethylamino)-phosphoranyliden)-phosphorictriamid-Et-imin

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Ihnen/SKUVerfügbarkeitPreis
1 mL
Warenkorb auf Verfügbarkeit prüfen
€ 214,00
5 mL
Warenkorb auf Verfügbarkeit prüfen
€ 612,00

Über diesen Artikel

Lineare Formel:
[(CH3)2N]3P=NP(=NC2H5)[N(CH3)2]2
CAS-Nummer:
Molekulargewicht:
339.40
UNSPSC Code:
12352000
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
7485991
Assay:
≥98.0% (NT)
Form:
liquid

€ 214,00


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Quality Segment

assay

≥98.0% (NT)

form

liquid

refractive index

n20/D 1.492

bp

96 °C/0.05 mmHg (lit.)

density

1.02 g/mL at at 25 °C (lit.), 1.02 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CCN=P(N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C

InChI

1S/C12H35N7P2/c1-12-13-20(15(2)3,16(4)5)14-21(17(6)7,18(8)9)19(10)11/h12H2,1-11H3

InChI key

CFUKEHPEQCSIOM-UHFFFAOYSA-N

Application

Phosphazene base P2-Et is an extremely strong, neutral nitrogen base. It gives excellent results where other bases fail

This strong non-ionic base has the ability to catalyze a wide variety of organic transformations such as:
  • Palladium-catalyzed cross-coupling reactions when used in combination with tBuXPhos or tBuBrettPhos G3 precatalysts.
  • Deprotonation of ortho-halobenzyl sulfones to generate α-sulfonyl benzylic carbanions.
  • Conversion of vinyl sufone to allyl sulfone.
  • α-Alkylation of 2-phenyl-2-oxazoline-4-carbonylcamphorsultam in the presence of tetrabutylammonium bromide.

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Dieser Artikel
794127941679421
description

≥98.0% (NT)

description

≥97.0%

description

~2.0 M in THF

description

~0.8 M in hexane

assay

≥98.0% (NT)

assay

≥97.0%

assay

-

assay

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

solution

form

liquid

density

1.02 g/mL at at 25 °C (lit.), 1.02 g/mL at 25 °C (lit.)

density

-

density

-

density

0.850-0.875 g/mL at 20 °C

refractive index

n20/D 1.492

refractive index

n20/D 1.474

refractive index

-

refractive index

-

bp

96 °C/0.05 mmHg (lit.)

bp

68 °C/0.05 mmHg (lit.)

bp

-

bp

-


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Lagerklasse

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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