751618

MorDalphos

97%

• Synonym(e): Di(1-adamantyl)-2-morpholinophenylphosphine
• Empirische Formel (Hill-System): C₃₀H₄₂NOP
• CAS-Nummer: 1237588-12-3
• Molekulargewicht: 463.63
• MDL-Nummer: MFCD17018759
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329766227
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 97%
• Form: solid
• Eignung der Reaktion: reagent type: ligand; reaction type: Arylations; reagent type: ligand; reaction type: Buchwald-Hartwig Cross Coupling Reaction
• mp (Schmelzpunkt): 219-224 °C
• Funktionelle Gruppe: phosphine
• Lagertemp.: 2-8°C
• SMILES String: C1CN(CCO1)c2ccccc2P([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
• InChI: 1S/C30H42NOP/c1-2-4-28(27(3-1)31-5-7-32-8-6-31)33(29-15-21-9-22(16-29)11-23(10-21)17-29)30-18-24-12-25(19-30)14-26(13-24)20-30/h1-4,21-26H,5-20H2/t21-,22+,23-,24-,25+,26-,29-,30-
• InChIKey: CCBRRSUORFMQCZ-BVIFAWIJSA-N

Beschreibung

Anwendung

MorDalphos is an electronically rich, sterically hindered P,N-based ancillary ligand developed by the Stradiotto group that can be used in the Buchwald-Hartwig Amination reaction[1], alkyne hydroamination[2] and monoarylation of compounds such as ammonia, hydrazine, and acetone.[3][4]

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable