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2-Di-tert.-butylphosphino-2′-(N,N-dimethylamino)-biphenyl

solid

Synonym(e):

tBu-DavePhos

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Über diesen Artikel

Empirische Formel (Hill-System):
C22H32NP
CAS-Nummer:
Molekulargewicht:
341.47
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Produktname

2-Di-tert.-butylphosphino-2′-(N,N-dimethylamino)-biphenyl,

form

solid

Quality Segment

reaction suitability

reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-X Bond Formation

mp

114-118 °C

functional group

phosphine

SMILES string

CN(C)c1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C

InChI

1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3

InChI key

PHLPNEHPCYZBNZ-UHFFFAOYSA-N

Application

Learn more about Buchwald Phosphine Ligands

Dialkylbiaryl phosphine ligand often used for Pd-catalyzed reactions in a range of contexts.

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Dieser Artikel
903701638021903663
description

-

description

1:1 THF adduct

description

97%

description

-

reaction suitability

reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-X Bond Formation, reagent type: ligand
reaction type: Arylations

reaction suitability

reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Buchwald-Hartwig Cross Coupling Reaction, core: palladium, reaction type: Stille Coupling

reaction suitability

reagent type: ligand
reaction type: Hydroaminations, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reaction type: Cross Couplings, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Kumada Coupling, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Arylations

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reagent type: catalyst
reaction type: Cross Couplings

form

solid

form

powder or crystals

form

-

form

powder or crystals

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

Quality Level

100

Quality Level

-

Quality Level

200

Quality Level

-

mp

114-118 °C

mp

-

mp

121-124 °C (lit.)

mp

>300 °C

2′-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine

palladium cross-coupling reagent tBuDavePhos Pd G3, tBuDavePhos Pd G3 ligand to palladium ratio control, third generation tBuDavePhos Pd G3, highly soluble tBuDavePhos Pd G3 in organic solvents, tBuDavePhos Pd G3 chemical, tBuDavePhos Pd G3 precatalyst, efficient tBuDavePhos Pd G3 for palladium catalysis, Buchwald tBuDavePhos Pd G3 catalyst, tBuDavePhos Pd G3 for laboratory use, air stable tBuDavePhos Pd G3 reagent, moisture stable tBuDavePhos Pd G3 for cross-coupling, tBuDavePhos Pd G3 catalyst loading optimization, tBuDavePhos Pd G3 for organic synthesis, tBuDavePhos Pd G3 long-life solution reagent

-

4th generation Buchwald precatalyst t-BuDavePhos Pd G4, t-BuDavePhos Pd G4 lab-grade, t-BuDavePhos Pd G4 chemical structure, t-BuDavePhos Pd G4 palladium catalyst, t-BuDavePhos Pd G4 for organic synthesis, t-BuDavePhos Pd G4 solvent compatibility, 1507403-97-5 t-BuDavePhos Pd G4, high purity t-BuDavePhos Pd G4 reagent, t-BuDavePhos Pd G4 cross-coupling catalyst, t-BuDavePhos Pd G4 for pharmaceutical applications, t-BuDavePhos Pd G4 reaction conditions


Piktogramme

Exclamation mark

Signalwort

Warning

Gefahrencodes

Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklasse

11 - Combustible Solids

Was ist los?

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

PSA (Persönliche Schutzausrüstung)

dust mask type N95 (US), Eyeshields, Gloves



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