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Sigma-Aldrich

Cerium(IV)-Oxid-Samarium-dotiert

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<0.5 μm particle size, powder, contains 20 mol % samarium as dopant

Synonym(e):

SDC, Samarium-dotiertes Cer(IV)oxid

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10 G
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10 G
€ 80,70

About This Item

Empirische Formel (Hill-System):
CeO2
Molekulargewicht:
172.11
MDL-Nummer:
UNSPSC-Code:
26111700
PubChem Substanz-ID:
NACRES:
NA.23

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Form

powder

Qualitätsniveau

Enthält

20 mol % samarium as dopant

Zusammensetzung

Sm0.2Ce0.8O1.9

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Oberflächenbereich

10-14 m2/g

Partikelgröße

0.1-0.5 μm (d50)
<0.5 μm

Schüttdichte

1.787 g/mL

Grünere Alternativprodukt-Kategorie

SMILES String

[Sm].O=[Ce]=O

InChI

1S/Ce.2O.Sm

InChIKey

AQGZISMLQKBRRO-UHFFFAOYSA-N

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Allgemeine Beschreibung

Cerium(IV) oxide-samarium doped powder (20% mol samarium doped) (SDC-20) is an electrolytic material with a high oxygen ion conductivity. Samarium ion acts as an aliovalent cation that can be incorporated into the host lattice to increase the oxygen vacancy concentration and improve the oxide ion conduction in cerium oxide. It can be synthesized by reverse strike co-precipitation technique.[1][2]
Samarium doped ceria may be used as an electrolyte in solid oxide fuel cells (SOFCs).[1][3] Electrical conductivity as a function of temperature of doped ceria was investigated in a study.[2] Relation of dopant type, oxygen vacancy ordering and ionic conductivity was investigated by transmission electron microscopy and electron energy loss spectroscopy.[4]
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Anwendung

Cerium(IV) oxide-samarium doped can be used in the fabrication of solid oxide fuel cells (SOFCs), which can further be used as environmentally-friendly sources of alternative energy.[5][6]

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Stephan Immenschuh et al.
Transplantation, 99(1), 56-62 (2014-08-15)
Treatment of patients with antibody-mediated rejection (AMR) after kidney transplantation by rituximab and plasmapheresis is ambiguous. Because of its unknown efficiency and serious side effects, biomarkers, which are predictive for responsiveness to this treatment in AMR patients, are required. Twenty
Intermediate-temperature electrochemical performance of a polycrystalline PrBaCo2O5+ δ cathode on samarium-doped ceria electrolyte.
Chen D, et al.
Journal of Power Sources, 188(1), 96-105 (2009)
Jun Zhang et al.
Scientific reports, 4, 7082-7082 (2014-11-19)
In this work, redox-active Mn or Cr is introduced to the B site of redox stable perovskite Sr(0.95)Ti(0.9)Nb(0.1)O3.00 to create oxygen vacancies in situ after reduction for high-temperature CO2 electrolysis. Combined analysis using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron
Diego H Sanchez et al.
PLoS genetics, 10(11), e1004806-e1004806 (2014-11-21)
Epigenetic mechanisms suppress the transcription of transposons and DNA repeats; however, this suppression can be transiently released under prolonged heat stress. Here we show that the Arabidopsis thaliana imprinted gene SDC, which is silent during vegetative growth due to DNA
Oxygen vacancy ordering in heavily rare-earth-doped ceria.
Ou DR, et al.
Applied Physics Letters, 89(17) (2006)

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