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696188
1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-yliden
97%, powder
Synonym(e):
1,3-Bis-(2,4,6-trimethylphenyl)-imidazol-2-yliden
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| Größe/SKU | Verfügbarkeit | Preis |
|---|---|---|
250 mg | Warenkorb auf Verfügbarkeit prüfen | € 59,40 € 44,55 |
1 g | Warenkorb auf Verfügbarkeit prüfen | € 171,00 |
Über diesen Artikel
€ 44,55
Listenpreis€ 59,40Sparen Sie 25%Produktname
1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-yliden, 97%
Quality Segment
assay
97%
form
powder
reaction suitability
reagent type: ligand
mp
140 °C
storage temp.
−20°C
SMILES string
Cc1cc(C)c(N2[C]N(C=C2)c3c(C)cc(C)cc3C)c(C)c1
InChI
1S/C21H24N2/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6/h7-12H,1-6H3
InChI key
JCYWCSGERIELPG-UHFFFAOYSA-N
Application
It can be used to synthesize:
- IMes ligated-rhodium complex as a catalyst for the selective hydrogenation of substituted aryl and heteroaryl boronate esters to cis-substituted borylated cycloalkanes.
- IMes/ruthenium complex (Cp*Ru(IMes)Cl)(Cp* =η5-C5Me3) as a catalyst for olefin ring closing metathesis reaction.
IMes is also used as an ancillary ligand in Pd-catalyzed Suzuki-Miyaura cross-coupling reaction between aryl chlorides or aryl triflates and arylboronic acids.
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Dieser Artikel | |||
|---|---|---|---|
| description 97% | description - | description 95% | description Umicore |
| reaction suitability reagent type: ligand | reaction suitability reagent type: ligand | reaction suitability core: gold, reagent type: catalyst | reaction suitability core: gold, reagent type: catalyst |
| assay 97% | assay - | assay 95% | assay - |
| form powder | form powder | form powder | form powder |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| storage temp. −20°C | storage temp. −20°C | storage temp. 2-8°C | storage temp. 2-8°C |
| mp 140 °C | mp 79-85 °C | mp >300 °C | mp 298 °C |
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Lagerklasse
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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