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Sigma-Aldrich

Basolite® F300

greener alternative

produced by BASF

Synonym(e):

Eisen-1,3,5-benzoltricarboxylat, Fe-BTC

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€ 181,00
100 G
€ 1.290,00

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10 G
€ 181,00
100 G
€ 1.290,00

About This Item

Empirische Formel (Hill-System):
C9H3FeO6
CAS-Nummer:
1195763-37-1
Molekulargewicht:
262.96
MDL-Nummer:
MFCD11656051
UNSPSC-Code:
26111700
PubChem Substanz-ID:
329761369
NACRES:
NA.23

€ 181,00

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Qualitätsniveau

100

Form

solid

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Oberflächenbereich

120-190 m2/g

Schüttdichte

0.16‑0.35 g/cm3

Grünere Alternativprodukt-Kategorie

, Enabling

SMILES String

O=C1O[Fe]2OC(=O)c3cc1cc(c3)C(=O)O2

InChI

1S/C9H6O6.Fe/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;/h1-3H,(H,10,11)(H,12,13)(H,14,15);/q;+3/p-3

InChIKey

UTYFBNKMZYRAFO-UHFFFAOYSA-K

Verwandte Kategorien

Allgemeine Beschreibung

Basolite®F300 (Fe-BTC) is a porous metal organic framework (MOF) that is used as a highly active catalyst for Lewis acid reactions such as acetalization of aldehydes and aldol condensation. It has a hybrid supertetrahedral build up from oxocentered trimmers of iron(III) octahedron that are connected by trimesate anions.[1]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Anwendung

Fe-BTC based MOF can be used in greener applications such as energy storage through lithium ion batteries. It can also be used in the supercritical adsorption of CO2.[2][3][4]

Rechtliche Hinweise

Basolite is a registered trademark of BASF SE

Piktogramme

Health hazardExclamation mark
GHS08,GHS07

Signalwort

Warning

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 2

Zielorgane

Eyes,Central nervous system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Zulassungslistungen

Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.

EU REACH Annex XVII (Restriction List)

CAS No.

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
STBJ5843
STBD9968V
S61151V
S61151
S58688

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2,6-Naphthalindicarbonsäure 99%

Sigma-Aldrich

523763

2,6-Naphthalindicarbonsäure

Facile synthesis of the Basolite F300-like nanoscale Fe-BTC framework and its lithium storage properties
Hu X, et al.
Royal Society of Chemistry Advances, 6(115), 114483-114490 (2016)
Comparison of porous iron trimesates basolite F300 and MIL-100 (Fe) as heterogeneous catalysts for lewis acid and oxidation reactions: roles of structural defects and stability
Dhakshinamoorthy A, et al.
ACS Catalysis, 2(10), 2060-2065 (2012)
A combined computational and experimental study of high pressure and supercritical CO2 adsorption on Basolite MOFs
Deniz E, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 175(115), 34-42 (2013)
Vijaya Ravinayagam et al.
Saudi journal of biological sciences, 27(7), 1726-1736 (2020-06-23)
Drug resistant bacteria affects millions worldwide and remains a serious threat to health care system. The study reports the first application of hybrid nanocomposites based on zeolitic imidazolate framework-8 (ZIF-8) with MFI structured zeolite Ti-ZSM-5 (TiZ5) and mesoporous carbon (MC).
Direct synthesis, structural features, and enhanced catalytic activity of the basolite F300-like semiamorphous Fe-BTC framework
Sanchez-Sanchez M, et al.
Crystal Growth & Design, 15(9), 4498-4506 (2015)
Alle zugehörigen Dokumente anzeigen

Artikel

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Questions

1–3 of 3 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. 物理的性質（例えば比表面積）の安定しているサンプルでしょうか？ 経時変化や劣化などはしないでしょうか？

    1 answer

    1. If the product is stored according to the SDS (i.e. tightly closed and dry), there should not be changes to the pore structure over time.

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