678503

(+)-Ipc₂B(allyl)boran -Lösung

1 M in pentane

• Synonym(e): (+)-B-Allyldiisopinocampheylboran -Lösung
• Lineare Formel: (C₁₀H₁₇)₂BCH₂CH=CH₂
• CAS-Nummer: 106356-53-0
• Molekulargewicht: 326.37
• MDL-Nummer: MFCD09038447
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 24885431
• NACRES: NA.22

Eigenschaften

• Optische Aktivität: [α]20/D +14°, c = 1 in pentane
• Konzentration: 1 M in pentane
• bp: 35-36 °C
• Dichte: 0.735 g/mL at 25 °C
• Lagertemp.: −20°C
• SMILES String: C[C@@H]1[C@H](C[C@H]2C[C@@H]1C2(C)C)B(CC=C)[C@H]3C[C@H]4C[C@@H]([C@@H]3C)C4(C)C
• InChI: 1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m0/s1
• InChIKey: ZIXZBDJFGUIKJS-AXSQLCHVSA-N

Beschreibung

Allgemeine Beschreibung

http://www.sigmaaldrich.com/ifb/acta/v35/acta-vol35-2002.html#32

Anwendung

This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.[1][2][3]

Sonstige Hinweise

Material may become hazy upon cooler storage, this will not affect use

Under refrigerator storage, these salt-free, Ipc₂B(allyl) reagents do not show any appreciable decrease in selectivity is observed after several months. They exhibit excellent reactivity and reactions can be performed at 5°C, even in water.[4]

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS07,GHS09
• Signalwort: Danger
• H-Sätze: H224,H304,H315,H319,H335,H336,H411
• P-Sätze: P210 - P233 - P273 - P301 + P310 - P331 - P403 + P233
• Gefahreneinstufungen: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Central nervous system, Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): -56.2 °F
• Flammpunkt (°C): -49 °C
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves