658308

Lithium-morpholinoborhydrid -Lösung

1 M in THF

• Empirische Formel (Hill-System): C₄H₁₁BLiNO
• CAS-Nummer: 144240-18-6
• Molekulargewicht: 106.89
• MDL-Nummer: MFCD07784406
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24884341

Eigenschaften

• Eignung der Reaktion: reagent type: reductant
• Konzentration: 1 M in THF
• Brechungsindex: n20/D 1.489
• Dichte: 0.877 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: [Li+].C[B-](C)(C)N1CCOCC1
• InChI: 1S/C4H11BNO.Li/c5-6-1-3-7-4-2-6;/h1-4H2,5H3;/q-1;+1
• InChIKey: FHKYRXRJDHFNMQ-UHFFFAOYSA-N

Beschreibung

Anwendung

Capable of reducing a variety of fuctional groups.[1][2][3][2]

LABs can transfer the amine moiety, as in the case of the reaction with halopyridines and primary alkyl methanesulfonates.[4][5]

Lithium Aminoborohydride (LAB) Reagents

• Reagent for reduction-amination reactions

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H261,H302,H314,H335,H336,H351
• P-Sätze: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 1.4 °F
• Flammpunkt (°C): -17 °C