577944

Hoveyda-Grubbs Katalysator^® M700

solid, Umicore

• Synonym(e): Dichloro-(o-isopropoxy-phenylmethylen)-(tricyclohexylphosphin)-ruthenium(II)
• Empirische Formel (Hill-System): C₂₈H₄₅Cl₂OPRu
• CAS-Nummer: 203714-71-0
• Molekulargewicht: 600.61
• UNSPSC Code: 12161600
• PubChem Substance ID: 24880901
• NACRES: NA.22
• MDL number: MFCD03453042

Eigenschaften

• Produktname: Hoveyda-Grubbs Katalysator^® M700, Umicore
• Quality Segment: 100
• product line: Grubbs Catalyst^® M700 Series
• form: solid
• reaction suitability: core: ruthenium, reaction type: Olefin Metathesis, reagent type: catalyst; reaction type: Ring Opening Metathesis Polymerisation
• manufacturer/tradename: Umicore Grubbs Catalyst^® M700 Series
• mp: 195-197 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: [H]\C(c1ccccc1OC(C)C)=[Ru](\Cl)Cl.C2CCC(CC2)P(C3CCCCC3)C4CCCCC4
• InChI: 1S/C18H33P.C10H12O.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)11-10-7-5-4-6-9(10)3;;;/h16-18H,1-15H2;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
• InChI key: KMKCJXPECJFQPQ-UHFFFAOYSA-L

Beschreibung

Application

Catalyst used in ring-closing metathesis with concomitant cis-vicinal dihyroxylation. Also employed in a pivotal, macrocyclic ring-closing metathesis in the multi-step synthesis of an HCV protease inhibitor.

Other Notes

Grubbs Catalyst^® Technology for Olefin Metathesis by Aldrich

Legal Information

Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions, please contact us at aldrich@sial.com or Materia at info@materia-inc.com

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Sicherheitshinweise

• Piktogramme: GHS02
• Signalwort: Warning
• Gefahrencodes: H228
• Sicherheitshinweise: P210 - P240 - P241 - P280 - P370 + P378
• Hazard Classifications: Flam. Sol. 2
• Lagerklasse: 4.1B - Flammable solid hazardous materials
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• PSA (Persönliche Schutzausrüstung): Eyeshields, Gloves, type N95 (US)