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530573

Sigma-Aldrich

Polypyrrol

doped, conductivity 30 S/cm (bulk), extent of labeling: 20 wt. % loading, composite with carbon black

Synonym(e):

Ppy

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25 G
€ 124,00

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25 G
€ 124,00

About This Item

CAS-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

€ 124,00


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Qualitätsniveau

Form

solid

Enthält

proprietary organic sulfonic acid as dopant

Kennzeichnungsgrad

20 wt. % loading

mp (Schmelzpunkt)

>300 °C

Löslichkeit

H2O: insoluble
organic solvents: insoluble

SMILES String

[nH]1cccc1

InChI

1S/C4H5N/c1-2-4-5-3-1/h1-5H

InChIKey

KAESVJOAVNADME-UHFFFAOYSA-N

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Allgemeine Beschreibung

Polypyrrole (PPy) is a conductive and highly stable polymer. It may be prepared by a standard electrochemical technique.[1] PPy may also be prepared by reacting β-napthalene sulfonic acid (NSA) and ammonium peroxo-disulphate in aqueous medium.[2] The charges on the surfaces can be easily modified by doping the polymer during its synthesis.[3]Solubility and conductivity measurements of PPy doped with camphor sulfonic and dodecyl benzene sulfonic acid has been reported.[4] Electrosensitivity and lower oxidation potential of PPy make it potentially useful for drug delivery, chemical sensors, batteries, ion selective electrodes, biosensor and biochemistry research. 5[5]
Polypyrrole (PPy) is a widely used heterocyclic polymer that is highly conductive and is majorly used in electrochemical applications. It is a cost efficient conducting polymer that has a stable oxidation and high solubility in water. It has a high degree of flexibility than polyaniline and has a density that facilitates a higher capacitance per unit volume.[6][7][8][9]

Anwendung

Conducting polymer.
Conductive additive for thermoplasitics and thermosets.
Inherently conducting polymer based additive. Loading of polypyrrole in carbon black typically 20%. Stable up to at least 300°C in air.
PPy is mainly used in the fabrication of a variety of electrochemical devices which include supercapacitors,[10][11] chemical sensors,[12] dye sensitized solar cells and lithium-ion batteries.[13]

Verpackung

Packaged in glass bottles

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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Conducting polymers with superhydrophobic effects as anticorrosion coating
Intelligent Coatings for Corrosion Control, 409-430 (2014)
Electrochemistry of nucleic acids and proteins, 1(1), 596-612 (2005)
Conducting polymers with superhydrophobic effects as anticorrosion coating
Intelligent Coatings for Corrosion Control edited by Atul Tiwari, Lloyd Hihara, James Rawlins, 409-430 (2014)
Monodisperse porous LiFePO4 microspheres for a high power Li-ion battery cathode
Sun C, et al.
Journal of the American Chemical Society, 133(7), 2132-2135 (2011)
Nanostructured conducting polymers and their biomedical applications
Wang GW, et al.
Journal of Nanoscience and Nanotechnology, 14(1), 596-612 (2014)

Artikel

The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

Self-healing soft electronic materials offer potential cost savings and reduced electronic waste.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

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Questions

  1. what is the density,molecular weight,and particle size.

    1 answer
    1. This product is supplied as an insoluble black solid. The material consists of approximately 80 percent carbon black, 20 percent polypyrrole, and a proprietary amount of an organic sulfonic acid dopant. The bulk density is not determined. Due to the high carbon black content, the compound is expected to be quite 'fluffy'. The molecular weight is also not determined. The average particle size is approximately 40 nm by Transmission Electron Microscopy (TEM) when fully dispersed. The powder form as provided is not dispersed and may form clumps or chunks.

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