498963

Isobutylzinkbromid -Lösung

0.5 M in THF

• Synonym(e): (2-Methylpropyl)zinc bromide, Bromo(2-methylpropyl)zinc
• Lineare Formel: (CH₃)₂CHCH₂ZnBr
• CAS-Nummer: 126403-67-6
• Molekulargewicht: 202.41
• NACRES: NA.22
• PubChem Substance ID: 24873242
• UNSPSC Code: 12352103
• MDL number: MFCD00671802
• eCl@ss: 32129103

Eigenschaften

• Quality Segment: 100
• concentration: 0.5 M in THF
• density: 0.943 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: CC(C)C[Zn]Br
• InChI: 1S/C4H9.BrH.Zn/c1-4(2)3;;/h4H,1H2,2-3H3;1H;/q;;+1/p-1
• InChI key: WYBHVVXVUCUWSE-UHFFFAOYSA-M

Beschreibung

Application

Isobutylzinc bromide is an organozinc compound, which can be used as a reagent in the palladium-catalyzed Negishi cross-coupling reaction to construct a carbon-carbon bond by reacting with aryl or heteroaryl halides . It is also used to prepare regioselective unsaturated ketones by reacting with tert-butyl isocyanide via an allylic carbonylative coupling reaction in the presence of a nickel catalyst.

Legal Information

Product of Rieke^® Metals, Inc.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• Gefahrencodes: H225,H261,H302,H315,H318,H335,H336,H351
• supp_hazards: EUH019
• Lagerklasse: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• Flammpunkt (°F): 1.4 °F - closed cup
• Flammpunkt (°C): -17.0 °C - closed cup
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react. 2
• Sicherheitshinweise: P210 - P231 + P232 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Zielorgane: Central nervous system, Respiratory system