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417599

Sigma-Aldrich

4-Methoxyphenylborsäure

≥95.0%

Synonym(e):

4-Methoxy-benzolboronsäure

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About This Item

Lineare Formel:
CH3OC6H4B(OH)2
CAS-Nummer:
5720-07-0
Molekulargewicht:
151.96
Beilstein:
2936912
MDL-Nummer:
MFCD00039139
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24866163
NACRES:
NA.22

Assay

≥95.0%

Form

powder

mp (Schmelzpunkt)

204-206 °C (lit.)

SMILES String

COc1ccc(cc1)B(O)O

InChI

1S/C7H9BO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3

InChIKey

VOAAEKKFGLPLLU-UHFFFAOYSA-N

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Verwandte Kategorien

Anwendung

Reagent used for
  • Suzuki-Miyaura cross-coupling reactions
  • Pd-catalyzed direct arylation
  • Highly effective synthesis using palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water
  • Palladium-catalyzed stereoselective Heck-type reaction
  • Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence
  • Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides
  • Ruthenium catalyzed direct arylation
  • Rh-catalyzed asymmetric conjugate addition
  • Ligand-free copper-catalyzed coupling

Reagent used in Preparation of
  • Palladium(II) thiocarboxamide complexes as Suzuki coupling catalyst
  • Push-pull arylvinyldiazine chromophores with photophysical properties

Sonstige Hinweise

enthält variable Anteile von Anhydrid

Piktogramme

Exclamation mark
GHS07

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Analysenzertifikate (COA)

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Mikhail Y Vorona et al.
Materials (Basel, Switzerland), 12(17) (2019-08-29)
Anthracene-based semiconductors are a class of molecules that have attracted interest due to their air stability, planarity, potential for strong intermolecular interactions, and favorable frontier molecular orbital energy levels. In this study seven novel 9,10-anthracene-based molecules were synthesized and their
Kosuke Ishijima et al.
Dalton transactions (Cambridge, England : 2003), 49(44), 15612-15621 (2020-09-24)
Benzo[b]arsole derivatives, being arsenic analogues of indole, were synthesized by utilizing a safely prepared arsenic precursor. The structural and photophysical properties of the obtained 2-arylbenzo[b]arsoles were experimentally and computationally studied in comparison with those of 1,2,5-triarylarsoles and 9-phenylarsafluorene. It was
Maria Makrinich et al.
Solid state nuclear magnetic resonance, 84, 196-203 (2017-05-06)
The ability of various pulse types, which are commonly applied for distance measurements, to saturate or invert quadrupolar spin polarization has been compared by observing their effect on magnetization recovery curves under magic-angle spinning. A selective central transition inversion pulse
Elangovan Sindhuja et al.
Dalton transactions (Cambridge, England : 2003), 41(17), 5351-5361 (2012-03-09)
A simple route to synthesise palladium(II) complexes from the reaction of N-substituted pyridine-2-thiocarboxamide ligands and PdCl(2)(PPh(3))(2) has been developed. The new complexes are very soluble in common solvents and have been fully characterised (elemental analysis, FT-IR, (1)H, (31)P, (13)C-NMR), including
M Lakshmi Kantam et al.
The Journal of organic chemistry, 71(25), 9522-9524 (2006-12-02)
N-Arylation of imidazoles and amines with arylboronic acids was accomplished with copper-exchanged fluorapatite (CuFAP) in methanol at room temperature. The products N-arylimidazoles and N-arylamines were isolated in good to excellent yields. A variety of arylboronic acids were converted to the
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