395099

Tris-(4-fluorphenyl)-phosphin

98%

• Synonym(e): Tri-(p-fluorophenyl)phosphine
• Lineare Formel: (FC₆H₄)₃P
• CAS-Nummer: 18437-78-0
• Molekulargewicht: 316.26
• UNSPSC Code: 12352101
• NACRES: NA.22
• PubChem Substance ID: 24864642
• MDL number: MFCD00013553
• Beilstein/REAXYS Number: 919838

Eigenschaften

• Quality Segment: 200
• assay: 98%
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 79-83 °C (lit.)
• functional group: phosphine
• greener alternative category: Aligned,
• SMILES string: Fc1ccc(cc1)P(c2ccc(F)cc2)c3ccc(F)cc3
• InChI: 1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
• InChI key: GEPJPYNDFSOARB-UHFFFAOYSA-N

Beschreibung

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Sicherheitshinweise

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Lagerklasse: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves