391115

N-(Phenylthio)-phthalimid

98%

• Empirische Formel (Hill-System): C₁₄H₉NO₂S
• CAS-Nummer: 14204-27-4
• Molekulargewicht: 255.29
• MDL-Nummer: MFCD00192396
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24864360

Eigenschaften

• Assay: 98%
• mp (Schmelzpunkt): 160-163 °C (lit.)
• Löslichkeit: DMSO: soluble 25 mg/mL, clear, yellow
• SMILES String: O=C1N(Sc2ccccc2)C(=O)c3ccccc13
• InChI: 1S/C14H9NO2S/c16-13-11-8-4-5-9-12(11)14(17)15(13)18-10-6-2-1-3-7-10/h1-9H
• InChIKey: NMHKBABHRKQHOL-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

N-(Phenylthio)phthalimide is an N-substituted phthalimide. It is used as a sulphenylating agent. The synthesis of N-(phenylthio)phthalimide has been reported.

Anwendung

N-(Phenylthio)phthalimide is suitable reagent used in the synthesis of phenyl (3-trimethoxysilylpropyl)-disulfide. It may be used in the sulfenylation of ylides and β−keto esters.
N-(Phenylthio)phthalimide may be used as sulfenylating agent in the synthesis of the following:

• α-phenylthio-ketones and α-phenylthio-aldehydes from aldehydes and ketones
• 3-sulfenyl indoles from indoles
• optically active 3-phenylthiooxindoles from unprotected 3-substituted oxindoles
• N−alkyl-β-phenylsulfenyl-2-acetylbenzimidazole from N−alkyl−2−acetylbenzimidazole
• N−phenylsulfenyl ketimines from oximes or nitro compounds

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable