377481

Isopropyltriphenylphosphoniumiodid

98%

• Synonym(e): (1-Methylethyl)triphenylphosphonium iodide, NSC 140615
• Lineare Formel: (CH₃)₂CHP(C₆H₅)₃I
• CAS-Nummer: 24470-78-8
• Molekulargewicht: 432.28
• NACRES: NA.22
• PubChem Substance ID: 24863508
• UNSPSC Code: 12352002
• EC Number: 246-281-5
• MDL number: MFCD00031595
• Assay: 98%
• Form: solid

Eigenschaften

• Quality Segment: 100
• assay: 98%
• form: solid
• reaction suitability: core: phosphonium, reaction type: C-C Bond Formation
• mp: 194-197 °C (lit.)
• functional group: phosphine
• SMILES string: [I-].CC(C)[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C21H22P.HI/c1-18(2)22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-18H,1-2H3;1H/q+1;/p-1
• InChI key: HHBXWXJLQYJJBW-UHFFFAOYSA-M

Beschreibung

Application

Reactant for:

• Total synthesis of heliananes
• Preparation of highly substituted benzene derivatives
• Synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents
• 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents
• Wittig reaction

Employed in Wittig and cyclopropanation reactions.

Sicherheitshinweise

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Lagerklasse: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves