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Palladium(II)-tetrafluoroborat Tetraacetonitril-Komplex

solid

greener alternative

Umweltfreundlichere Alternative

Synonym(e):

Tetrakis(acetonitril)palladium(II)

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Größe/SKUVerfügbarkeitPreis
250 mg
Warenkorb auf Verfügbarkeit prüfen
€ 67,10
1 g
Warenkorb auf Verfügbarkeit prüfen
€ 258,00

Über diesen Artikel

Lineare Formel:
Pd(CH3CN)4(BF4)2
CAS-Nummer:
Molekulargewicht:
444.24
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

€ 67,10


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Produktname

Palladium(II)-tetrafluoroborat Tetraacetonitril-Komplex,

form

solid

Quality Segment

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium, reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

230 °C (dec.) (lit.)

greener alternative category

SMILES string

[Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F

InChI

1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2

InChI key

YWMRPVUMBTVUEX-UHFFFAOYSA-N

General description

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.
We are committed to providing greener alternatives that adhere to the 12 Principles of Green Chemistry. This precatalyst serves as a highly active precatalyst for cross-coupling reactions, enabling efficient C-C and C-N bond formation with reduced catalyst loading, thus aligns with Green Chemistry principle "Catalysis". Click here for more information.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:
  • Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands

Precursor for:
  • Synthesis of dendritic SCS-pincer palladium complexes
  • Palladium complexes of click ligands
  • Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination

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Dieser Artikel
446319412740299685
description

-

description

99.99%

description

-

description

97%

reaction suitability

reagent type: ligand, reaction type: Heck Reaction, reagent type: catalyst
core: palladium, reaction type: Hiyama Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reaction type: Cross Couplings, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reaction type: Negishi Coupling

reaction suitability

core: palladium, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Heck Reaction, reagent type: catalyst

reaction suitability

reagent type: catalyst, reaction type: Negishi Coupling, reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Hiyama Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Negishi Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, core: palladium, reaction type: Suzuki-Miyaura Coupling, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Cross Couplings, reagent type: catalyst
reaction type: C-H Activation

form

solid

form

powder

form

solid

form

solid

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

200

mp

230 °C (dec.) (lit.)

mp

-

mp

-

mp

~220 °C


Piktogramme

Exclamation mark

Signalwort

Warning

Gefahrencodes

Hazard Classifications

Acute Tox. 4 Inhalation

Lagerklasse

11 - Combustible Solids

Was ist los?

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

PSA (Persönliche Schutzausrüstung)

dust mask type N95 (US), Eyeshields, Gloves



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the purity of this chemical? And how much percentage of chloride (Cl-) or bromide ion (Br-) is contented in this chemical?

    1 answer
    1. The purity of this item is not tested for this item. The percentage of Chloride and Bromide is not on the COA and not tested for.

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