335002

Carbonyldihydridotris(triphenylphosphin)ruthenium(II)

• Synonym(e): Dihydridocarbonyltris(triphenylphosphine)ruthenium
• Lineare Formel: [(C₆H₅)₃P]₃Ru(CO)H₂
• CAS-Nummer: 25360-32-1
• Molekulargewicht: 919.79
• MDL number: MFCD00015870
• UNSPSC Code: 12352202
• PubChem Substance ID: 24860277
• NACRES: NA.22

Eigenschaften

• Quality Segment: 100
• reaction suitability: core: ruthenium, reagent type: catalyst; reaction type: C-H Activation
• sustainability: Sustainability features
• mp: 161-163 °C (lit.)
• SMILES string: [RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
• InChI: 1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;
• InChI key: MLIYPCQSOXNTLJ-UHFFFAOYSA-N

Beschreibung

General description

We are committed to providing greener alternatives that adhere to the 12 Principles of Green Chemistry. This versatile phosphine ligand enables efficient transition metal-catalyzed cross-coupling reactions with enhanced selectivity and reduced byproduct formation, thus aligns with Green Chemistry principle "Catalysis". Click here for more information.

Application

• Catalyst for conversion of 1,4-alkynediols into pyrroles
• Catalyst for oxidation of primary alcohols to methyl esters
• Catalyst for rearrangement of oximes to amides
• Catalyst for C-C coupling via directed C-H activation
• Catalyst for enyne cyclization

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• Gefahrencodes: H302 + H312 + H332
• Sicherheitshinweise: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• Lagerklasse: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• PSA (Persönliche Schutzausrüstung): dust mask type N95 (US), Eyeshields, Gloves