325058

(S)-(+)-3-Brom-2-methyl-1-propanol

97%

• Synonym(e): (2S)-3-Bromo-2-methyl-1-propanol, (S)-3-Bromo-2-methylpropan-1-ol, (S)-3-Hydroxy-2-methylpropyl bromide
• Lineare Formel: BrCH₂CH(CH₃)CH₂OH
• CAS-Nummer: 98244-48-5
• Molekulargewicht: 153.02
• Beilstein: 4738280
• MDL-Nummer: MFCD00064575
• UNSPSC-Code: 12352101
• PubChem Substanz-ID: 24859484
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Form: liquid
• Optische Aktivität: [α]25/D +7.3°, c = 2 in chloroform
• Brechungsindex: n20/D 1.483 (lit.)
• Dichte: 1.461 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: bromo; hydroxyl
• SMILES String: C[C@@H](CO)CBr
• InChI: 1S/C4H9BrO/c1-4(2-5)3-6/h4,6H,2-3H2,1H3/t4-/m1/s1
• InChIKey: KIBOHRIGZMLNNS-SCSAIBSYSA-N

Beschreibung

Anwendung

(S)-(+)-3-Bromo-2-methyl-1-propanol is a precursor to synthesize the phase II mexiletine metabolite, (R)-mexiletine N-carbonyloxy-β-D-glucuronide.[1] It can be used in the synthesis of (R)-(+)-muscopyridine,[2] polycavernoside A[3] and (+)-allopumiliotoxin 323B′.[4] It can also be employed in building homochiral porous molecular networks.[5]

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 197.6 °F - closed cup
• Flammpunkt (°C): 92 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter