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258784

Sigma-Aldrich

Coproporphyrin I -dihydrochlorid

synthetic

Synonym(e):

3,8,13,18-Tetramethyl-2-H,23H-porphin-2,7,12,17-tetrapropionsäure -dihydrochlorid

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About This Item

Empirische Formel (Hill-System):
C36H38N4O8 · 2HCl
CAS-Nummer:
69477-27-6
Molekulargewicht:
727.63
MDL-Nummer:
MFCD00013469
UNSPSC-Code:
12161600
PubChem Substanz-ID:
24855660
NACRES:
NA.22

Form

solid

Eignung der Reaktion

core: porphyrin
reagent type: catalyst

λmax

395 nm

SMILES String

Cl.Cl.Cc1c(CCC(O)=O)c2cc3[nH]c(cc4nc(cc5[nH]c(cc1n2)c(CCC(O)=O)c5C)c(CCC(O)=O)c4C)c(CCC(O)=O)c3C

InChI

1S/C36H38N4O8.2ClH/c1-17-21(5-9-33(41)42)29-14-26-19(3)23(7-11-35(45)46)31(39-26)16-28-20(4)24(8-12-36(47)48)32(40-28)15-27-18(2)22(6-10-34(43)44)30(38-27)13-25(17)37-29;;/h13-16,37,40H,5-12H2,1-4H3,(H,41,42)(H,43,44)(H,45,46)(H,47,48);2*1H/b25-13-,26-14-,27-15-,28-16-,29-14-,30-13-,31-16-,32-15-;;

InChIKey

XROPZSRTTZKNQB-ARSPAUKVSA-N

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Allgemeine Beschreibung

Coproporphyrin I dihydrochloride belongs to the porphyrin group, and it is used as a starting material to synthesize monofunctional and phosphorescent metalloporphyrin labeling reagents.

Anwendung

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Sigma-Aldrich

P1134

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PORPHYRIN I AldrichCPR

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Sigma-Aldrich

51280

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Platin-Oktaethylporphyrin 95%

Sigma-Aldrich

673625

Platin-Oktaethylporphyrin

5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphin 97%

Sigma-Aldrich

257613

5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphin

R Giovannetti et al.
Talanta, 42(12), 1913-1918 (1995-12-01)
The reagent 3,8,13,18-tetramethyl-21H,23H-porphine-2,7,12,17-tetrapropionic acid or coproporphyrin-I (CPI) was used for the spectrophotometric determination of copper(II) and cobalt(II) in the presence of pyridine and imidazole catalysts. Optimum conditions were investigated and the methods were applied to the determination of parts per
Krzysztof Kilian et al.
Talanta, 60(4), 669-678 (2008-10-31)
The reaction of 5,10,15,20-tetrakis(4-carboxylphenyl)porphyrin (TCPP) with Cd(II), Pb(II), Hg(II) and Zn(II) was studied spectrophotometrically and kinetics, equilibrium constants as well as photodecomposition of complexes were determined. It was verified that these metal ions with large radius accelerate the incorporation reaction
R Giovannetti et al.
Talanta, 46(5), 977-984 (2008-10-31)
The reaction of 3,8,13,18-tetramethyl-21H,23H-porphine-2,7,12,17-tetrapropionic acid or coproporphyrin-I (CPI) with mercury(II) was studied spectrophotometrically, and kinetic and equilibrium constants were determined; the influence of temperature on the reaction rate was also studied. It was verified that mercury(II) accelerates the incorporation reaction
Rita Giovannetti et al.
Talanta, 63(4), 857-864 (2008-10-31)
The reaction of 3,8,13,18-tetramethyl-21H,23H-porphine-2,7,12,17-tetrapropionic acid or coproporphyrin-I (CPI) with the elements of 11 group have been studied. CPI is an anionic porphyrin that slowly reacts with copper ion to form Cu(II)CPI and with silver ions to form Ag(II)CPI, Ag(III)CPI complexes
Preparation of monofunctional and phosphorescent palladium (II) and platinum (II) coproporphyrin labeling reagents
Journal of Porphyrins and Phthalocyanines, 5(10), 735-741 (2001)

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