237582

Methyl-2-phenylsulfinylacetat

98%

• Lineare Formel: C₆H₅S(O)CH₂CO₂CH₃
• CAS-Nummer: 14090-83-6
• Molekulargewicht: 198.24
• Beilstein: 1953383
• EG-Nummer: 237-936-6
• MDL-Nummer: MFCD00002087
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24854255
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: solid
• bp: 130-131 °C/0.5 mmHg (lit.)
• mp (Schmelzpunkt): 52-54 °C (lit.)
• SMILES String: COC(=O)CS(=O)c1ccccc1
• InChI: 1S/C9H10O3S/c1-12-9(10)7-13(11)8-5-3-2-4-6-8/h2-6H,7H2,1H3
• InChIKey: JPPXZUDQIXZLIL-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

Anwendung

Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): 235.4 °F - closed cup
• Flammpunkt (°C): 113 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)