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213969

(−)-Diethyl-D-tartrat

≥99%

Synonym(e):

(−)-Diethyl-D-tartrat

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5 G

€ 48,60

25 G

€ 79,00

€ 48,60


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Über diesen Artikel

Lineare Formel:
HO2CCCH(OH)CH(OH)CO2H
CAS-Nummer:
Molekulargewicht:
206.19
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
237-458-8
Beilstein/REAXYS Number:
1727143
MDL number:
Assay:
≥99%

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Quality Level

assay

≥99%

optical activity

[α]23/D −8.5°, neat

optical purity

ee: ≥99% (GLC)

refractive index

n20/D 1.446 (lit.)

bp

162 °C/19 mmHg (lit.)

density

1.205 g/mL at 20 °C (lit.)

functional group

ester, hydroxyl

SMILES string

CCOC(=O)[C@@H](O)[C@H](O)C(=O)OCC

InChI

1S/C8H14O6/c1-3-13-7(11)5(9)6(10)8(12)14-4-2/h5-6,9-10H,3-4H2,1-2H3/t5-,6-/m0/s1

InChI key

YSAVZVORKRDODB-WDSKDSINSA-N

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Dieser Artikel
227803163457420395
assay

≥99%

assay

98%

assay

99%

assay

99%

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

bp

162 °C/19 mmHg (lit.)

bp

-

bp

163 °C/23 mmHg (lit.)

bp

105-107 °C/1 mmHg (lit.)

density

1.205 g/mL at 20 °C (lit.)

density

1.119 g/mL at 20 °C (lit.)

density

1.238 g/mL at 25 °C (lit.)

density

0.972 g/mL at 25 °C (lit.)

refractive index

n20/D 1.446 (lit.)

refractive index

n20/D 1.439 (lit.)

refractive index

-

refractive index

n20/D 1.428 (lit.)

optical activity

[α]23/D −8.5°, neat

optical activity

[α]23/D −17°, neat

optical activity

[α]22/D +21°, c = 2.5 in H2O

optical activity

[α]20/D −57°, c = 1 in chloroform

Application

(-)-Diethyl D-tartrate can be used as a starting material in the synthesis of bioactive compounds such as (-)-kumausallene, syringolide 2 and (+)-exo-brevicomin.

Lagerklasse

10 - Combustible liquids

wgk

WGK 3

flash_point_f

200.1 °F - closed cup

flash_point_c

93.4 °C - closed cup

ppe

Eyeshields, Gloves


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Besitzen Sie dieses Produkt bereits?

In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Synthesis and absolute configuration of syringolide 2, an elicitor from Pseudomonas syringae pv. tomato.
Kuwahara S, et al.
Tetrahedron Letters, 36(18), 3201-3202 (1995)
A new expeditious synthesis of (+)-exo-brevicomin via efficient C? C bond formation of triflates.
Kotsuki H, et al.
Tetrahedron Letters, 30(30), 3999-4000 (1989)
Radical cyclization of ?-alkoxyacrylates: A formal synthesis of (-)-kumausallene.
Lee E, et al.
Tetrahedron Letters, 39(3), 317-318 (1998)
Naoto Hama et al.
Organic letters, 13(4), 616-619 (2011-01-05)
A first total synthesis of broussonetine F from diethyl L-tartrate was achieved. The cornerstone of our synthesis was an orthoamide Overman rearrangement, which provided an allylic amino alcohol with complete diastereoselectivity.
Aman Ullah et al.
Biomacromolecules, 12(10), 3826-3832 (2011-09-06)
Poultry feather quills have been extruded in a twin screw extruder with sodium sulfite treatment as a reducing agent. The effect of four different plasticizers (ethylene glycol, propylene glycol, glycerol, and diethyl tartrate) on the thermoplastic properties was then investigated.

Global Trade Item Number

SKUGTIN
213969-500G04061837639098
213969-5G04061837639104
213969-25G04061838773029

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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