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Chrysanthemylalkohol, cis-trans Gemisch
98%
Synonym(e):
2,2-Dimethyl-3-(2-methylpropenyl)-cyclopropan-methanol, Chrysanthemol
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About This Item
Lineare Formel:
(CH3)2C3H2[CH=C(CH3)2]CH2OH
CAS-Nummer:
Molekulargewicht:
154.25
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
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Assay
98%
Brechungsindex
n20/D 1.475 (lit.)
bp
66-69 °C/0.07 mmHg (lit.)
Dichte
0.888 g/mL at 25 °C (lit.)
SMILES String
C\C(C)=C\C1C(CO)C1(C)C
InChI
1S/C10H18O/c1-7(2)5-8-9(6-11)10(8,3)4/h5,8-9,11H,6H2,1-4H3
InChIKey
HIPIENNKVJCMAP-UHFFFAOYSA-N
Allgemeine Beschreibung
Oxidation of chrysanthemyl alcohol in the presence of [RuO4]2- yields chrysantheniic acid.
Anwendung
Chrysanthemyl alcohol was used in the determination of position of double bonds in various terepenes and branched chain compounds.
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A B Attygalle et al.
Analytical chemistry, 65(18), 2528-2533 (1993-09-15)
The electron-impact mass spectra of alpha, beta-bis(methylthio) derivatives of certain terpenes and other compounds with branched alkenyl groups contain diagnostic peaks that can be used for locating the position of the double bond in the parent compound. In contrast to
Oxo complexes of ruthenium (VI) and (VII) as organic oxidants.
Green G, et al.
Journal of the Chemical Society. Perkin Transactions 1, 681-686 (1984)
L Y Mou et al.
Journal of Asian natural products research, 3(2), 103-116 (2001-06-16)
Chrysanthemol (1), a trans-eudesmane type sesquiterpene from Chrysanthemum indicum L., possesses certain anti-inflammatory activity. Its total synthesis was approached from two alternative routes and finally accomplished in ten steps from R-(+)-carvone via alpha-eudesmol (10) as the key intermediate. The overall
[Studies on the chemical constituents of Chrysanthemum indicum L].
D Q Yu et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 22(11), 837-840 (1987-11-01)
Gas chromatographic determination of racemic cis- and trans-chrysanthemols and their potential aldehyde and carboxylic acid microbial metabolites.
M Miski et al.
Journal of chromatography, 437(2), 436-441 (1988-03-25)
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