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Sigma-Aldrich

Luperox® DI, tert-Butylperoxid

98%

Synonym(e):

Di-tert.-butylperoxid, tert.-Butylperoxid

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About This Item

Lineare Formel:
(CH3)3COOC(CH3)3
CAS-Nummer:
110-05-4
Molekulargewicht:
146.23
Beilstein:
1735581
EG-Nummer:
203-733-6
MDL-Nummer:
MFCD00008803
UNSPSC-Code:
12352120
PubChem Substanz-ID:
24850244
NACRES:
NA.22

Dampfdruck

40 mmHg ( 20 °C)

Assay

98%

Form

liquid

Eignung der Reaktion

reagent type: oxidant

Brechungsindex

n20/D 1.3891 (lit.)

bp

109-110 °C (lit.)

Dichte

0.796 g/mL at 25 °C (lit.)

Lagertemp.

2-8°C

SMILES String

CC(C)(C)OOC(C)(C)C

InChI

1S/C8H18O2/c1-7(2,3)9-10-8(4,5)6/h1-6H3

InChIKey

LSXWFXONGKSEMY-UHFFFAOYSA-N

Verwandte Kategorien

Anwendung

Luperox®DI, tert-Butyl peroxide has been used as a radical initiator to induce free radical polymerization. It has also been used as a cetane enhancer in a study to determine the phase behavior of carboxylate-based extended surfactant reverse micellar microemulsions with ethanol and vegetable oil/diesel blends.

Rechtliche Hinweise

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Piktogramme

FlameHealth hazard
GHS02,GHS08

Signalwort

Danger

Gefahreneinstufungen

Aquatic Chronic 3 - Flam. Liq. 2 - Muta. 2 - Org. Perox. E

Lagerklassenschlüssel

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

Flammpunkt (°F)

42.8 °F - closed cup

Flammpunkt (°C)

6 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

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Geun-Tae Yun et al.
Science advances, 4(8), eaat4978-eaat4978 (2018-08-29)
Both high static repellency and pressure resistance are critical to achieving a high-performance omniphobic surface. The cuticles of springtails have both of these features, which result from their hierarchical structure composed of primary doubly reentrant nanostructures on secondary microgrooves. Despite
A Mortensen et al.
FEBS letters, 426(3), 392-396 (1998-05-26)
Peroxyl radicals, as model for peroxyl radicals formed during autoxidation of lipids, have been generated in three solvent systems (cyclohexane, tetrahydrofuran and tert-butanol/water) by steady-state and laser flash photolysis, and their reaction with beta-carotene studied. Steady-state photolysis experiments showed that
Carson T Riche et al.
Nature communications, 7, 10780-10780 (2016-02-24)
The translation of batch chemistries onto continuous flow platforms requires addressing the issues of consistent fluidic behaviour, channel fouling and high-throughput processing. Droplet microfluidic technologies reduce channel fouling and provide an improved level of control over heat and mass transfer
B H Shen et al.
Science advances, 5(7), eaaw4856-eaaw4856 (2019-07-25)
Electrochemical reduction of lithium ion battery electrolyte on Si anodes was mitigated by synthesizing nanoscale, conformal polymer films as artificial solid electrolyte interface (SEI) layers. Initiated chemical vapor deposition (iCVD) was used to deposit poly(1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane) (pV4D4) onto silicon thin film
Hironori Kitaguchi et al.
Journal of the American Chemical Society, 127(18), 6605-6609 (2005-05-05)
Well-resolved ESR spectra of free pentadienyl radicals have been observed under photoirradiation of di-tert-butylperoxide (Bu(t)OOBu(t)) and polyunsaturated fatty acids in the absence of O(2), allowing us to determine the hfc values. The hfc values of linoleyl radical indicate that the
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