Enantioselective hydrolysis and ammonolysis of dimethyl-3-hydroxyglutarate has been studied using immobilized lipase B isolated from Candidaantarctica[1].
Anwendung
Dimethyl 3-hydroxyglutarate was used in the synthesis of two chiral fragments representing C1-11 and C12-25 of the polyene macrolide pimaricin[2].
A convergent synthetic strategy for the polyene macrolide pimaricin.
Brooks DW and Palmer JT.
Tetrahedron Letters, 24(30), 3059-3062 (1983)
Enantioselective enzymatic preparation of chiral glutaric monocarboxylic acids and amides.
Jacobsen EE, et al.
Journal of Molecular Catalysis. B, Enzymatic, 21(1), 55-58 (2003)
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