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Merck

117854

Sigma-Aldrich

Trioctylphosphin

technical grade, 90%

Synonym(e):

TOP, P(Oct)3

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4 X 25 ML
€ 109,00
100 ML
€ 156,00
500 ML
€ 691,00
2.5 L
€ 1.800,00

€ 109,00


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4 X 25 ML
€ 109,00
100 ML
€ 156,00
500 ML
€ 691,00
2.5 L
€ 1.800,00

About This Item

Lineare Formel:
[CH3(CH2)7]3P
CAS-Nummer:
Molekulargewicht:
370.64
Beilstein:
1776995
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352001
PubChem Substanz-ID:
NACRES:
NA.22

€ 109,00


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Qualität

technical grade

Assay

90%

Eignung der Reaktion

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Brechungsindex

n20/D 1.468 (lit.)

bp

284-291 °C/50 mmHg (lit.)

Dichte

0.831 g/mL at 25 °C (lit.)

Funktionelle Gruppe

phosphine

SMILES String

CCCCCCCCP(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChIKey

RMZAYIKUYWXQPB-UHFFFAOYSA-N

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Anwendung

Trioctylphosphin kann zur Umwandlung von metallischen Nanokristallen, Schüttgut-Pulvern, Folien, Drähten und dünnen Beschichtungen in Metallphosphide verwendet werden.[1] Außerdem kann es als Lösungsmittel und Stabilisator bei der Synthetisierung von Cadmiumsulfid-Nanostäbchen aus Cadmiumacetat und Schwefel genutzt werden.[2]

Verpackung

Die 25-ml-Sure/Seal Flasche wird für den Einmalgebrauch empfohlen. Wiederholte Einstiche führen höchstwahrscheinlich zu einer Leistungsminderung des Produkts.

Rechtliche Hinweise

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Piktogramme

Corrosion

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Skin Corr. 1B

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 2

Flammpunkt (°F)

296.6 °F - closed cup

Flammpunkt (°C)

147 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

Synthesis and characterization of nearly monodisperse CdE (E= sulfur, selenium, tellurium) semiconductor nanocrystallites.
Murray C
Journal of the American Chemical Society, 115(19), 8706-8715 (1993)
Synthesis of cdses nanocrystals in coordinating and noncoordinating solvents: Solvent's role in evolution of the optical and structural properties.
Al-Salim N
Chemistry of Materials, 19(21), 5185-5193 (2007)
Yuhuan Ji et al.
Analytical chemistry, 87(11), 5500-5504 (2015-05-07)
Bottom-up proteomics is a powerful tool for characterization of protein post-translational modifications (PTMs), where PTMs are identified at the peptide level by mass spectrometry (MS) following protein digestion. However, enzymatic digestion is associated with additional sample processing steps that may
Liam R Bradshaw et al.
Nano letters, 15(2), 1315-1323 (2015-01-15)
Luminescent solar concentrators (LSCs) harvest sunlight over large areas and concentrate this energy onto photovoltaics or for other uses by transporting photons through macroscopic waveguides. Although attractive for lowering solar energy costs, LSCs remain severely limited by luminophore reabsorption losses.
Neha Arora et al.
Physical chemistry chemical physics : PCCP, 16(23), 11381-11389 (2014-05-07)
Here we present digestive ripening facilitated interatomic diffusion for the phase controlled synthesis of homogeneous intermetallic nanocrystals of Au-Sn system. Au and Sn metal nanoparticles synthesized by a solvated metal atom dispersion (SMAD) method are employed as precursors for the

Artikel

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

Verwandter Inhalt

The Catalexis platform enhances catalysis by digitally optimizing catalyst selection to identify the most effective phosphine ligands for cross-coupling reactions.

Die Catalexis-Plattform verbessert die Katalyse durch digitale Optimierung der Katalysatorauswahl, um die effektivsten Phosphinliganden für Kreuzkupplungsreaktionen zu identifizieren.

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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