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Merck

P13800

Sigma-Aldrich

1-Phenylethanol

98%

Sinónimos:

(±)-1-Phenylethanol, (±)-α-Methylbenzyl alcohol, Methyl phenyl carbinol, Styrallyl alcohol, Styrene alcohol

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25 G
US$ 46,50
500 G
US$ 152,00
1 KG
US$ 203,00

US$ 46,50

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25 G
US$ 46,50
500 G
US$ 152,00
1 KG
US$ 203,00

About This Item

Fórmula lineal:
C6H5CH(OH)CH3
Número de CAS:
Peso molecular:
122.16
Beilstein:
1905149
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
NACRES:
NA.22

US$ 46,50

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densidad de vapor

4.21 (vs air)

Nivel de calidad

presión de vapor

0.1 mmHg ( 20 °C)

Ensayo

98%

índice de refracción

n20/D 1.527 (lit.)

bp

204 °C/745 mmHg (lit.)

mp

19-20 °C (lit.)

densidad

1.012 g/mL at 25 °C (lit.)

cadena SMILES

CC(O)c1ccccc1

InChI

1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3

Clave InChI

WAPNOHKVXSQRPX-UHFFFAOYSA-N

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Aplicación

  • 1-Phenylethanol can be used in the acid catalyzed Ritter reaction to synthesize various N-benzylacetamides.[1][2]
  • It is one of the key precursors for the synthesis of [60] fullerene-fused isochroman derivatives via palladium-catalyzed hydroxyl-directed cyclization.[3]
  • It is used in Friedlander synthesis of quinolines where 1-phenylethanol reacts with 2-aminobenzylic alcohol derivatives to yield corresponding quinones.[4]
  • It can also be used in the regioselective, iridium-catalyzed multicomponent synthesis of pyrimidines.[5]

Aplicación

Referencia del producto
Descripción
Precios

Pictogramas

Exclamation mark

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Eye Irrit. 2

Código de clase de almacenamiento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

187.9 °F - Pensky-Martens closed cup

Punto de inflamabilidad (°C)

86.6 °C - Pensky-Martens closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Transition-metal-free indirect friedlander synthesis of quinolines from alcohols.
Martinez R, et al.
The Journal of Organic Chemistry, 73(24), 9778-9780 (2008)
Synthesis of [60] fullerene-fused tetrahydrobenzooxepine and isochroman derivatives via hydroxyl-directed C?H activation/C?O cyclization.
Zhai W Q, et al.
Organic Letters, 16(6), 1638-1641 (2014)
FeCl3-catalyzed Ritter reaction. Synthesis of amides.
Anxionnat B, et al.
Tetrahedron Letters, 50(26), 3470-3473 (2009)
A sustainable multicomponent pyrimidine synthesis.
Deibl N, et al.
Journal of the American Chemical Society, 137(40), 12804-12807 (2015)
The Ritter reaction under truly catalytic Br?nsted acid conditions.
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European Journal of Organic Chemistry, 2007(28), 4642-4645 (2007)

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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