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Merck

359009

Sigma-Aldrich

Cerium(IV) sulfate

Sinónimos:

Ceric sulfate, Cerium disulfate

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About This Item

Fórmula lineal:
Ce(SO4)2
Número de CAS:
Peso molecular:
332.24
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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form

powder

Quality Level

reaction suitability

core: cerium
reagent type: catalyst

density

3.01 g/mL at 25 °C (lit.)

SMILES string

[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4

InChI key

VZDYWEUILIUIDF-UHFFFAOYSA-J

Application

Cerium(IV) sulfate can be used to catalyze:
  • Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.[1]
  • Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.[2]
  • Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.[3]

Reactant for:
  • Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions

  • Oxidizing agent

Other Notes

may contain excess sulfate

pictograms

CorrosionEnvironment

signalword

Danger

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Hidayat Hussain et al.
Chemistry & biodiversity, 12(2), 289-294 (2015-02-14)
A new polychlorinated triphenyl diether named microsphaerol (1), has been isolated from the endophtic fungus Microsphaeropsis sp. An intensive phytochemical investigation of the endophytic fungus Seimatosporium sp., led to the isolation of a new naphthalene derivative named seimatorone (2) and
S M Sultan et al.
Journal of pharmaceutical and biomedical analysis, 7(3), 279-286 (1989-01-01)
A simple and accurate kinetic method for the determination of propranolol has been developed. Cerium(IV) sulphate (0.5 M) is used to oxidize propranolol in 2 M sulphuric acid at room temperature to the ketone form that absorbs light at a
A Porvali et al.
Waste management (New York, N.Y.), 107, 66-73 (2020-04-12)
Efficient recovery of REEs present in the battery waste is a modern problem that has proven to be difficult to solve in an efficient manner. The raw material investigated in the current study is mixed alkaline rare earth element (REE)
John H T Luong et al.
The journal of physical chemistry. B, 109(4), 1400-1407 (2006-07-21)
A simple wet chemical method involving only ultrasonic processing in dilute ceric sulfate (CS) was used to functionalize carbon nanotubes (CNTs). Unexpectedly, single-walled and multiwalled carbon nanotubes (SWCNTs and MWCNTs) were cut, oxidized, and disintegrated by sonication in 0.1 N
Toshio Yao et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(6), 829-833 (2003-07-02)
A flow injection biosensor system was proposed for the highly sensitive detection of 2,4,6-trichlorophenol (2,4,6-TCP). The system is based on the preoxidation by ceric sulfate to the corresponding benzoquinone (2,6-dichloro-1,4-benzoquinone: 2,6-DC-1,4-BQ), which was characterized using cyclic voltammetry, hydrodynamic voltammetry, and

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    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Is it powder?

    1 answer
    1. This physical form of this product may be powder or chunks. Please see the link below to review the product specifications:
      https://www.sigmaaldrich.com/specification-sheets/178/533/359009-BULK_______ALDRICH__.pdf

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