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131377

Sigma-Aldrich

1,10-Phenanthroline

≥99%

Sinónimos:

o-phenanthroline

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About This Item

Fórmula empírica (notación de Hill):
C12H8N2
Número de CAS:
66-71-7
Peso molecular:
180.21
EC Number:
200-629-2
MDL number:
MFCD00011678
UNSPSC Code:
12352100
eCl@ss:
39210124
PubChem Substance ID:
24848008
NACRES:
NA.22

assay

≥99%

form

powder

mp

114-117 °C (lit.)

SMILES string

c1cnc2c(c1)ccc3cccnc23

InChI

1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H

InChI key

DGEZNRSVGBDHLK-UHFFFAOYSA-N

Gene Information

human ... FNTA(2339)

Categorías relacionadas

Application

1,10-Phenanthroline can be used as:
  • A cathode buffer layer to improve the efficiency of organic solar cells.
  • A conventional chelator to study its efficacy in Fenton′s reaction-luminol chemiluminescence system.
  • A ligand in mild, copper (II)-catalyzed cross-coupling of organoboronic acids and sulfinate salts, leading to aryl- and alkenylsulfones.
  • A versatile ligand employed in the spectrophotometric determination of metals and photocatalytic reduction of carbon dioxide.
  • A building block for metallomacrocycles.

pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

signalword

Danger

hcodes

H301,H410

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Mitsuhiro Wada et al.
Luminescence : the journal of biological and chemical luminescence, 29(7), 955-958 (2014-01-10)
In vitro screening of a Fe(2+) -chelating effect using a Fenton's reaction-luminol chemiluminescence (CL) system is described. The luminescence between the reactive oxygen species generated by the Fenton's reaction and luminol was decreased on capturing Fe(2+) using a chelator. The
Catalysis by Metal Complexes, 14, 217-217 (1993)
Aswan Sci. Technol. Bull., 13, 3-3 (1992)
Chunming Sun et al.
ACS applied materials & interfaces, 6(2), 739-744 (2014-01-07)
We reported a significant improvement in the efficiency of organic solar cells by introducing hybrid TiO2:1,10-phenanthroline as a cathode buffer layer. The devices based on polymer thieno[3,4-b]thiophene/benzodithiophene:[6,6]-phenyl C71-butyric acid methyl ester (PTB7:PC71BM) with hybrid buffer layer exhibited an average power
Savo Lazic et al.
Photochemistry and photobiology, 93(5), 1248-1258 (2017-04-04)
Cancer remains a major global malaise requiring the advent of new, efficient and low-cost treatments. Photodynamic therapy, which combines a photosensitizer and photons to produce cytotoxic reactive oxygen species, has been established as an effective cancer treatment but has yet
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