298336

3-(Perfluorobutyryl)-(−)-camphor

98%

• Synonym(s): 3-(Heptafluorobutyryl)-L-camphor, 3-Heptafluorobutyryl-(−)-camphor
• Empirical Formula (Hill Notation): C₁₄H₁₅F₇O₂
• CAS Number: 115224-00-5
• Molecular Weight: 348.26
• Beilstein: 2306496
• MDL number: MFCD00003747
• UNSPSC Code: 12352115
• PubChem Substance ID: 24857977
• NACRES: NA.22

Properties

• Assay: 98%
• optical activity: [α]19/D −123°, c = 2.6 in chloroform
• refractive index: n20/D 1.422 (lit.)
• density: 1.218 g/mL at 25 °C (lit.)
• SMILES string: CC1(C)C2CC[C@]1(C)C(=O)C2C(=O)C(F)(F)C(F)(F)C(F)(F)F
• InChI: 1S/C14H15F7O2/c1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m0/s1
• InChI key: PEWOESYEGLBLNR-NSMOOJLNSA-N

Description

Application

3-(Perfluorobutyryl)-(−)-camphor can be used:

• To prepare mesoporous metal-organic hybrid materials, which are used as catalysts in the asymmetric hetero-Diels-Alder cyclization of Danishefsky′s diene with benzaldehydes.
• As a precursor in the synthesis of chiral tetrakis(β-diketonate) Ln(III) complexes.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 199.4 °F - closed cup
• Flash Point(C): 93 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves