471933
4-Iodophenylboronic acid
≥95.0%
Synonym(s):
B-(4-iodophenyl)-boronic acid, p-Iodophenylboronic acid, p-iodo-benzeneboronic acid
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About This Item
Recommended Products
Quality Level
Assay
≥95.0%
mp
326-330 °C (lit.)
functional group
iodo
SMILES string
OB(O)c1ccc(I)cc1
InChI
1S/C6H6BIO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChI key
PELJYVULHLKXFF-UHFFFAOYSA-N
Related Categories
Application
Reagent used for
Reagent used in Preparation of
- Copper-mediated ligandless aerobic fluoroalkylation
- Palladium-catalyzed aerobic oxidative cross-coupling reactions
- Recyclable magnetic-nanoparticle-supported palladium catalyst for the Suzuki coupling reactions
- Oxidative hydroxylation using a copper (Cu) catalyst
- Ligand-free palladium-catalyzed Suzuki-Miyaura cross-coupling
- Homocoupling using gold salts as a catalyst
- Ruthenium (Ru)-catalyzed cross-coupling
- CuI-catalyzed Suzuki coupling reactions
- Palladium-catalyzed domino Heck-Mizoroki/Suzuki-Miyaura reactions
- Manganese triacetate-mediated radical additions of arylboronic acids to alkenes
Reagent used in Preparation of
- Pleuromutilin derivatives for ribosomal binding and antibacterial activity via "Click Chemistry"
- Liquid crystalline polyacetylene derivatives
Other Notes
Contains varying amounts of anhydride
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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CuI-catalyzed Suzuki coupling reaction of organoboronic acids with alkynyl bromides
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Three iodinated phenylboronic acids have been synthesized: 4-iodophenylboronic acid (2a), 3-(4-iodobenzenesulfonamido)phenylboronic acid (5a) and 3-(5-dimethylamino-6-iodo-1-naphthalenesulfonamido)phenylboronic acid (6a). The corresponding no-carrier-added 125I derivatives 2b, 5b and 6b have been prepared in good yield by selective displacement of the tributylstannyl group. Compound
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Copper-catalysed oxidative hydroxylation of arylboronic acids was accomplished in water containing an amphiphilic surfactant, providing facile access to phenol derivatives.
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