932191
SPhos ChemBeads
solid
Synonym(s):
2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl, S Phos, SPhos
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About This Item
Product Name
SPhos ChemBeads,
Quality Level
product line
ChemBeads
form
solid
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
greener alternative category
SMILES string
P(C4CCCCC4)(C3CCCCC3)c1c(cccc1)c2c(cccc2OC)OC
InChI
1S/C26H35O2P/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21/h9-11,16-21H,3-8,12-15H2,1-2H3
1 of 1
This Item | |||
|---|---|---|---|
| reaction suitability reagent type: catalyst | reaction suitability - | reaction suitability - | reaction suitability reagent type: catalyst |
| form solid | form - | form powder or crystals | form solid |
| Quality Level 100 | Quality Level 300 | Quality Level - | Quality Level 100 |
| product line ChemBeads | product line Buchwald Ligand | product line - | product line ChemBeads |
| greener alternative product characteristics Catalysis | greener alternative product characteristics Waste Prevention | greener alternative product characteristics Catalysis | greener alternative product characteristics - |
| sustainability Greener Alternative Product | sustainability Greener Alternative Product | sustainability Greener Alternative Product | sustainability - |
General description
Application
- Palladium catalyzed Suzuki-Miyaura cross-coupling reaction between Boc-protected aminomethyltrifluoroborate and aryl chlorides or hetaryl chlorides to form the corresponding aminomethylarenes.
- Palladium catalyzed Suzuki-Miyaura cross-coupling reaction between 4-methyl-substituted piperidinylzinc reagent and different aryl or heteroaryl iodides to form various substituted piperidines.
- Intramolecular Suzuki-Miyaura coupling to form the 18-membered macrocyclic ring during the multi-step synthesis of riccardin C.
Highly universal ligand for Suzuki-Miyaura coupling; aryl chlorides, hindered biaryls, heterobiaryls.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
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Product is also available as neat ligand (638072)
comparable product
related product
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 932191-1G | 04065269195337 |
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