If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
47633
Fmoc-Leu-OH
≥97.0%
Synonym(s):
N-(9-Fluorenylmethoxycarbonyl)-L-leucine, Fmoc-L-leucine
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| Pack Size | SKU | Availability | Price |
|---|
About This Item
Quality Level
assay
≥97.0%
optical activity
[α]20/D −25±2°, c = 1% in DMF
reaction suitability
reaction type: C-H Activation, reaction type: Fmoc solid-phase peptide synthesis, reagent type: ligand
reaction type: Peptide Synthesis
mp
152-156 °C
application(s)
peptide synthesis
functional group
Fmoc, amine, carboxylic acid
storage temp.
2-8°C
SMILES string
CC(C)C[C@H](NC(=O)OCC1c2ccccc2-c3ccccc13)C(O)=O
InChI
1S/C21H23NO4/c1-13(2)11-19(20(23)24)22-21(25)26-12-18-16-9-5-3-7-14(16)15-8-4-6-10-17(15)18/h3-10,13,18-19H,11-12H2,1-2H3,(H,22,25)(H,23,24)/t19-/m0/s1
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This Item | |||
|---|---|---|---|
| assay ≥97.0% | assay ≥98.0% | assay ≥98.0% (T) | assay 95% |
| functional group Fmoc, carboxylic acid, amine | functional group Fmoc, amine, carboxylic acid | functional group Fmoc, amine, carboxylic acid | functional group Fmoc, amine, carboxylic acid |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
| mp 152-156 °C | mp 124-127 °C | mp 145-147 °C (lit.) | mp 147-153 °C (lit.) |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| optical activity [α]20/D −25±2°, c = 1% in DMF | optical activity - | optical activity [α]20/D −12±1°, c = 1% in DMF | optical activity [α]20/D −18°, c = 1 in DMF |
Application
- Various oligopeptides by reacting with functionalized α-amino acid hydrochloride salts.
- A cyclic depsipeptide sansalvamide A, a natural product found in marine fungus.
- Streptocidin A−D, decapeptide antibiotics naturally found in Streptomyces sp. Tü 6071.
- Coumaroyl dipeptide amide that can be used for cosmetic applications.
Biochem/physiol Actions
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 47633-50G-F | 04061832362366 |
| 47633-5G-F | 04061832642581 |
| 47633-1KG-F | 04061826222744 |
| 47633-250G-F | 04061832362359 |
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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