If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
177261
DPPF
97%, powder
Synonym(s):
1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 g | Available to ship TODAYfromMILWAUKEE | $42.00 | |
| 10 g | Available to ship TODAYfromMILWAUKEE | $233.00 | |
| 25 g | Available to ship TODAYfromMILWAUKEE | $401.00 |
About This Item
$42.00
Available to ship TODAYDetails
Product Name
DPPF, 97%
assay
97%
form
powder
reaction suitability
reaction type: Cross Couplings, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Carbonylations, reagent type: ligand
reaction type: Ene Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Tsuji-Trost Reaction
greener alternative product characteristics
Catalysis
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Greener Alternative Product
mp
181-182 °C (dec.) (lit.)
functional group
phosphine
greener alternative category
SMILES string
[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI
1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;
InChI key
HPXNTHKXCYMIJL-UHFFFAOYSA-N
General description
Application
Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology
1 of 1
This Item | |||
|---|---|---|---|
| reaction suitability reaction type: Cross Couplings, reagent type: ligand | reaction suitability - | reaction suitability reaction type: Cross Couplings, reagent type: ligand | reaction suitability reaction type: Cross Couplings, reagent type: ligand |
| assay 97% | assay - | assay - | assay 97% |
| form powder | form solid | form solid | form solid |
| functional group phosphine | functional group - | functional group phosphine | functional group phosphine |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 181-182 °C (dec.) (lit.) | mp 181-182 °C (dec.) (lit.) | mp 73-75 °C | mp 261 °C (lit.) |
Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Related Content
Phosphine Ligand Application Guide
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 177261-25G | 04061833544839 |
| 177261-10G | 04061838753182 |
| 177261-250G | 04061833472729 |
| 177261-1G | 04061838753199 |
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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