Skip to Content
MilliporeSigma
All Photos(1)

Documents

345105

Sigma-Aldrich

Ethylmagnesium bromide solution

1.0 M in tert-butyl methyl ether

Synonym(s):

Bromoethylmagnesium

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
CH3CH2MgBr
CAS Number:
925-90-6
Molecular Weight:
133.27
Beilstein/REAXYS Number:
3587203
MDL number:
MFCD00000043
UNSPSC Code:
12352103
PubChem Substance ID:
24861294
NACRES:
NA.22

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in tert-butyl methyl ether

density

0.841 g/mL at 25 °C

SMILES string

CC[Mg]Br

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

InChI key

TWTWFMUQSOFTRN-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

Application


  • Solution Structure and Magnesium Deposition Electrochemistry of Mixing Alkylmagnesium Halide with Magnesium Sulfonyl Amide/Glyme Solution: This research explores the electrochemical behavior of ethylmagnesium bromide in mixed solutions for magnesium deposition applications (Egashira & Hiratsuka, 2016).

  • Ethyl magnesium bromide as an efficient anionic initiator for controlled polymerization of ε-caprolactone: The article investigates the use of ethylmagnesium bromide as an initiator for the controlled polymerization of ε-caprolactone (Malinová & Brožek, 2014).

  • Room temperature electrodeposition of metallic magnesium from ethylmagnesium bromide in tetrahydrofuran and ionic liquid mixtures: This research focuses on the electrodeposition of metallic magnesium using ethylmagnesium bromide in various solvent mixtures (Chen et al., 2015).

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 1

flash_point_f

-29.2 °F - closed cup

flash_point_c

-34 °C - closed cup

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
T Nishiyama et al.
Chemical & pharmaceutical bulletin, 48(12), 1999-2002 (2001-01-06)
The direct alpha-bromination of various ketones using trifluoromethanesulfonic anhydride and Grignard reagent or magnesium bromide in ether gave the corresponding alpha-bromo ketones in moderate to good yields under mild reaction conditions.
F Turon et al.
Lipids, 37(8), 817-821 (2002-10-10)
An analytical procedure was developed for regiodistribution analysis of TAG using alpha-MAG prepared by an ethyl magnesium bromide deacylation. In the present communication, the deacylation procedure is shown to lead to representative alpha-MAG, allowing the composition of the native TAG
R G Xie et al.
Steroids, 55(11), 488-490 (1990-11-01)
The reaction of ethyl magnesium bromide and 17 alpha-ethynylestradiol with formaldehyde in the presence of triethyl phosphate or hexamethylphosphoramide gave the 2- and 4-formyl-17 alpha-ethynylestradiol in high yield. Treatment of the formyl derivatives with an alkaline solution of hydrogen peroxide
Yuichi Kobayashi et al.
Organic letters, 7(2), 183-186 (2005-01-14)
[Reaction: see text] Low regioselectivity of RMgBr (R = aryl, alkenyl) in the CuCN-catalyzed reaction with 4-cyclopentene-1,3-diol monoacetate is improved by addition of LiCl or MgCl2 to a similar extent as previously obtained with RMgCl (>90:10). The limitation encountered in
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service