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431400

Phosphomolybdic acid hydrate

≥99.99% trace metals basis

Synonym(s):

Molybdophosphoric acid

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10 g
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$308.00
$231.00
50 g
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$1,110.00
$832.50

About This Item

Linear Formula:
H3[P(Mo3O10)4] · xH2O
CAS Number:
Molecular Weight:
1825.25 (anhydrous basis)
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
234-713-5
MDL number:
Assay:
≥99.99% trace metals basis
Form:
crystals

$231.00

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Quality Segment

assay

≥99.99% trace metals basis

form

crystals

reaction suitability

reagent type: oxidant

impurities

≤0.01% insolubles, <100 ppm total metallic impurities

density

1.62 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.02%, sulfate (SO42-): ≤0.025%

cation traces

Ca: ≤0.02%, Fe: ≤0.005%, NH4+: ≤0.01%, heavy metals: ≤0.005%

SMILES string

O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O

InChI

1S/12Mo.H3O4P.H2O.36O/c;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;(H3,1,2,3,4);1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;

InChI key

PDDXOPNEMCREGN-UHFFFAOYSA-N

General description

Phosphomolybdic acid hydrate is a heteropolyacid hydrate. It participates in the synthesis of molybdenum disulfide (MoS2)-reduced graphene oxide (RGO) composites. Phosphomolybdic acid is one of the components of the Goldner′s trichrome stain used for tissue staining.[1]

Application

A precursor to hybrid organic-inorganic based molecular batteries with applications as cation-insertion electrodes.
Employed in preparation of a hybrid organic-inorganic, electroactive material with potential application as a cation-insertion electrode in batteries.
Reactant for preparation of:
  • Catalysts for the nitration of aromatic compounds
  • Highly dispersed MoOx/CNTs (carbon nanotubes) as a support for Pt catalysts[2]
  • Reduced molybdophosphate mixed-valence Keggin clusters[3]
  • Polyoxometalate (POM) hybrid materials based on Keggin polyanion building blocks
  • Luminescent Langmuir-Blodgett films
  • Anchored Wilkinson catalyst

Features and Benefits

Meets A.C.S. reagent specifications.

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This Item
221856795601.93022
assay

≥99.99% trace metals basis

assay

-

assay

-

assay

-

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

form

crystals

form

crystals

form

crystals

form

-

anion traces

chloride (Cl-): ≤0.02%, sulfate (SO42-): ≤0.025%

anion traces

chloride (Cl-): ≤0.02%, sulfate (SO42-): ≤0.025%

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤100 mg/kg

anion traces

-

density

1.62 g/mL at 25 °C (lit.)

density

1.62 g/mL at 25 °C (lit.)

density

1.62 g/mL at 25 °C (lit.)

density

1.62 g/mL at 25 °C (lit.)

impurities

≤0.01% insolubles, <100 ppm total metallic impurities

impurities

≤0.01% insolubles

impurities

-

impurities

-


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signalword

Danger

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

pictograms

Corrosion

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials



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Tomoyuki Akutagawa et al.
Inorganic chemistry, 50(14), 6711-6718 (2011-06-16)
Hydrogen-bonded assemblies of the two-electron reduced mixed-valence Keggin clusters [PMo(12)O(40)](5-) and [SiMo(12)O(40)](6-) were obtained by the one-pot electron-transfer reactions between p-phenylenediamine (PPD) or 2,3,5,6-tetramethyl-PPD (TMPPD) (donors) and H(+)(3)[PMo(12)O(40)](3-) or H(+)(4)[SiMo(12)O(40)](4-) (acceptors) in CH(3)CN. The redox states of the [PMo(12)O(40)](5-) and
Zhi Ming Cui et al.
Chemical communications (Cambridge, England), 47(29), 8418-8420 (2011-06-28)
HPMo self-assembly on carbon nanotubes followed by decomposition is used to fabricate highly dispersed MoO(x)/CNTs as a support for high performance of a Pt catalyst towards methanol oxidation.
MoS2-reduced graphene oxide composites via microwave assisted synthesis for sodium ion battery anode with improved capacity and cycling performance.
Qin W, et al.
Electrochimica Acta, 153, 55-61 (2015)



Global Trade Item Number

SKUGTIN
431400-10G04061832108278
431400-50G04061838195890

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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