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309443

(±)-1,3-Butanediol

anhydrous, ≥99%

Synonym(s):

1,3-Butylene glycol

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Pack SizeSKUAvailabilityPrice
100 mL

Available to ship TODAYfromMILWAUKEE

$66.80
1 L

Available to ship TODAYfromMILWAUKEE

$135.00

About This Item

Linear Formula:
CH3CH(OH)CH2CH2OH
CAS Number:
Molecular Weight:
90.12
UNSPSC Code:
12352001
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-529-7
Beilstein/REAXYS Number:
1731276
MDL number:
Assay:
≥99%
Grade:
anhydrous
Bp:
203-204 °C (lit.)
Vapor pressure:
0.06 mmHg ( 20 °C)

$66.80


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grade

anhydrous

Quality Segment

vapor density

3.1 (20 °C, vs air)

vapor pressure

0.06 mmHg ( 20 °C)

assay

≥99%

form

(Liquid or Viscous Liquid)

autoignition temp.

741 °F

expl. lim.

0.34-6.3 %

impurities

<0.003% water, <0.005% water (100 mL pkg)

refractive index

n20/D 1.44 (lit.)

pH

6.0-7.0 (20 °C)

bp

203-204 °C (lit.)

mp

-54 °C

density

1.005 g/mL at 25 °C (lit.)

SMILES string

CC(O)CCO

InChI

1S/C4H10O2/c1-4(6)2-3-5/h4-6H,2-3H2,1H3

InChI key

PUPZLCDOIYMWBV-UHFFFAOYSA-N

Application

(±)-1,3-Butanediol may be used as a solvent in the preparation of 6-methoxy-2-benzoxazolinone via condensation reaction between 2-hydroxy-4-methoxyphenyJarnmonium chloride and urea. It can also react with carboxylic acids to form the corresponding chlorohydrin esters in the presence of chlorotrimethylsilane.

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This Item
B84904B84785
Quality Level

100

Quality Level

200

Quality Level

200

assay

≥99%

assay

98%

assay

≥99.45% (GC), 99.5%

grade

anhydrous

grade

-

grade

-

form

(Liquid or Viscous Liquid)

form

liquid

form

liquid

expl. lim.

0.34-6.3 %

expl. lim.

-

expl. lim.

-

vapor pressure

0.06 mmHg ( 20 °C)

vapor pressure

-

vapor pressure

0.06 mmHg ( 20 °C)


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Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

226.4 °F - closed cup

flash_point_c

108 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)



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Kamarza Mulia et al.
Molecules (Basel, Switzerland), 24(3) (2019-02-15)
Mangosteen (Garcinia mangostana L.) is a fruit that is rich in xanthones, utilized as health supplements or additives in food products due to their high antioxidant activities. Choline chloride (ChCl)-based deep eutectic solvents (DESs) with polyalcohols (ethylene glycol, glycerol, propanediols
Access to (S)-2-methyloxetane and the precursor (S)-1, 3-butanediol of high enantiomeric purity.
Hintzer K, et al.
The Journal of Organic Chemistry, 47(20), 3850-3854 (1982)
6-methoxy-2-benzoxazolinone synthesis in 1,3-butanediol.
Richey JD, et al.
Agricultural and Biological Chemistry, 40(12), 2413-2416 (1976)



Global Trade Item Number

SKUGTIN
309443-1L04061826675922
309443-100ML04061826675908

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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