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P27127

Phenylmercuric acetate

97%

Synonym(s):

Phenylmercury acetate, Mercury phenyl acetate

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Pack SizeSKUAvailabilityPrice
25 g
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$65.50

About This Item

Linear Formula:
C6H5HgOCOCH3
CAS Number:
62-38-4
Molecular Weight:
336.74
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24898353
EC Number:
200-532-5
Beilstein/REAXYS Number:
3662930
MDL number:
MFCD00008691

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Quality Segment

200

assay

97%

form

powder

mp

148-151 °C (lit.)

SMILES string

CC(=O)O[Hg]c1ccccc1

InChI

1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1

InChI key

XEBWQGVWTUSTLN-UHFFFAOYSA-M

Application

Phenylmercuric acetate (PMA) can react with a palladium salt such as palladium acetate to form an arylpalladium salt in situ, which then reacts with primary or secondary allylic alcohols to produce 3-aryl aldehydes. It can also be used in the multi-step synthesis of 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl thiol via Floyd′s pathway.

Disclaimer

For U.S. Customers: Contains mercury; Do not place in trash - dispose according to local, state, or federal laws.

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This Item
176109833521.04410
Phenylmercuric acetate 97%

Sigma-Aldrich

P27127

Phenylmercuric acetate

Mercury(II) acetate ACS reagent, ≥98.0%

Sigma-Aldrich

176109

Mercury(II) acetate

Mercury(II) acetate puriss. p.a., ACS reagent, ≥99.0% (precipitation titration)

Sigma-Aldrich

83352

Mercury(II) acetate

Mercury(II) acetate for analysis EMSURE® ACS,Reag. Ph Eur

Supelco

1.04410

Mercury(II) acetate

assay

97%

assay

≥98.0%

assay

≥99.0% (precipitation titration)

assay

≥99.0% (complexometric)

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

300

mp

148-151 °C (lit.)

mp

179-182 °C (lit.)

mp

179-182 °C (lit.)

mp

178-180 °C (decomposition)

form

powder

form

powder

form

powder or crystals

form

solid

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1

target_organs

Kidney,Central nervous system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP1914
BCCK8520
BCCH7651
BCCJ6355
BCCD1001

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Related Content

Synthesis of aromatic and indole alpha-glucosinolates.
Vo Quan V, et al.
Carbohydrate Research, 455, 45-53 (2018)
The arylation of allylic alcohols with organopalladium compounds. A new synthesis of 3-aryl aldehydes and ketones.
Heck R F, et al.
Journal of the American Chemical Society, 90(20), 5526-5531 (1968)
Harry J Beaulieu et al.
Journal of occupational and environmental hygiene, 5(6), 360-366 (2008-03-28)
Phenyl mercuric acetate (PMA) historically has been used as a catalyst in polyurethane systems. In the 1950s-1970s, PMA was used as a catalyst in the 3M Tartan brand polyurethane flexible floors that were installed commonly in school gymnasiums. Mercury vapor
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Global Trade Item Number

SKUGTIN
P27127-25G04061834365198

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