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29580

Sigma-Aldrich

cis,cis-1,5-Cyclooctadiene

≥98.0% (GC)

Synonym(s):

COD

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About This Item

Empirical Formula (Hill Notation):
C8H12
CAS Number:
1552-12-1
Molecular Weight:
108.18
Beilstein/REAXYS Number:
1209288
EC Number:
216-291-4
MDL number:
MFCD00001752
UNSPSC Code:
12352100
PubChem Substance ID:
57648379

assay

≥98.0% (GC)

refractive index

n20/D 1.493

solubility

water: soluble 0.05 g/L

density

0.880 g/mL at 20 °C (lit.)

SMILES string

C1CC=CCCC=C1

InChI

1S/C8H12/c1-2-4-6-8-7-5-3-1/h1-2,7-8H,3-6H2/b2-1-,8-7-

InChI key

VYXHVRARDIDEHS-QGTKBVGQSA-N

General description

Surface grafting of cis,cis-1,5-cyclooctadiene (cyclic olefin) with low strain energy was explored using ring-opening metathesis polymerization in the vapor phase[1]. The inclusion complex of cis,cis-1,5-cyclooctadiene with β-cyclodextrin (β-CD) was studied by using proton NMR spectroscopy[2].

Application

cis,cis-1,5-Cyclooctadiene (COD) has been employed as ligand:
  • during regio- and stereoselective synthesis of (Z)-1,2-dihaloalkenes[3]
  • in the preparation of metal complexes, e.g. bis-COD-nickel, a versatile reagent for preparing (PI)-allylnickel halides[4]

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

89.6 °F - closed cup

flash_point_c

32 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCBL2155V
1369462V
1369462
429961/1
368430/1

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Jiaying Zhao et al.
Population health metrics, 15(1), 37-37 (2017-10-01)
Valid and comparable cause of death (COD) statistics are crucial for health policy analyses. Variations in COD assignment across geographical areas are well-documented while socio-institutional factors may affect the process of COD and underlying cause of death (UCD) determination. This
Pietro Carlozzi et al.
Journal of biotechnology, 303, 37-45 (2019-07-28)
Consecutive dark-fermentation and photo-fermentation stages were investigated for a profitable circular bio-economy. H2 photo-production versus poly(3-hydroxybutyrate) (P3HB) accumulation is a modern biotechnological approach to use agro-food industrial byproducts as no-cost rich-nutrient medium in eco-sustainable biological processes. Whey and molasses are
Beibei Zhou et al.
Environmental science and pollution research international, 26(24), 24683-24694 (2019-06-27)
The effects of plant-based carbon source addition on wastewater NO3--N removal and the involved microorganisms, especially denitrifying bacteria, were investigated. A synthetic wastewater (NO3--N, 15 mg/L) was treated through the batch experiment, which included three inoculation cycles (7 days/cycle), and
Jingxin Zhang et al.
Scientific reports, 7(1), 11293-11293 (2017-09-14)
Powdered activated carbon (AC) is commonly used as an effective additive to enhance anaerobic digestion (AD), but little is known about how the metabolic pathways resulting from adding AC change the microbial association network and enhance food waste treatment. In
Qilin Wang et al.
Environmental science & technology, 51(17), 9800-9807 (2017-08-05)
Biological nitrogen removal through the nitrite pathway (NH
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