209058
Rhodium(II) acetate dimer
powder
Synonym(s):
Rh2(OAc)4, Dirhodium tetraacetate, Tetrakis(acetato)dirhodium(II)
Sign Into View Organizational & Contract Pricing
Select a Size
50 MG
$104.00
250 MG
$305.00
1 G
$779.45
2 G
$1,630.00
25 G
$14,160.00
All Photos(3)
Select a Size
Change View
50 MG
$104.00
250 MG
$305.00
1 G
$779.45
2 G
$1,630.00
25 G
$14,160.00
About This Item
Linear Formula:
Rh2(OOCCH3)4
CAS Number:
Molecular Weight:
441.99
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
![Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)] 95%](/deepweb/assets/sigmaaldrich/product/structures/102/178/d1171a49-0358-406b-8b32-04324dbf9c02/640/d1171a49-0358-406b-8b32-04324dbf9c02.png)
form
powder
Quality Level
reaction suitability
core: rhodium
reagent type: catalyst
SMILES string
CC(=O)O[Rh]OC(C)=O.CC(=O)O[Rh]OC(C)=O
InChI
1S/4C2H4O2.2Rh/c4*1-2(3)4;;/h4*1H3,(H,3,4);;/q;;;;2*+2/p-4
InChI key
SYBXSZMNKDOUCA-UHFFFAOYSA-J
Looking for similar products? Visit Product Comparison Guide
General description
Rhodium(II) acetate dimer is an effective catalyst for carbenoid reactions, hydrocarbon oxidation, hydroboration, and nitrene reactions.[1]
Application
Effective catalyst for ylide formation.
Homogeneous catalyst.[2]
Used in an efficient synthesis of ß-hydroxy-α-arylacrylates involving the decomposition of diazoetster intermediates with concomitant 1,2-arylmigration.[3]
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Customers Also Viewed
Sugimura, T.; Mori, A.
Tetrahedron Asymmetry, 14, 881-881 (2003)
Carter, D.S. Van Vranken, D.L.
Tetrahedron Letters, 40, 1617-1617 (1999)
Aldrichimica Acta, 15, 13-13 (1982)
Dirhodium(II) Tetraacetate
Michael P, et al.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Doyle, M. P.
Chemical Reviews, 86, 919-919 (1986)
Active Filters
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service
