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218790

Tetraphenylphosphonium chloride

98%, solid

Synonym(s):

Chlorotetraphenylphosphorane

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5 g

Available to ship TODAYfromMILWAUKEE

$137.00
10 g

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$161.00
50 g

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$344.00

About This Item

Linear Formula:
(C6H5)4P(Cl)
CAS Number:
2001-45-8
Molecular Weight:
374.84
NACRES:
NA.22
PubChem Substance ID:
24853089
UNSPSC Code:
12352002
EC Number:
217-890-3
MDL number:
MFCD00011916
Beilstein/REAXYS Number:
3922393

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Product Name

Tetraphenylphosphonium chloride, 98%

Quality Level

200

assay

98%

form

solid

reaction suitability

core: phosphonium

mp

272-274 °C (lit.)

SMILES string

[Cl-].c1ccc(cc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1

InChI key

WAGFXJQAIZNSEQ-UHFFFAOYSA-M

Application

  • Tetraphenylphosphonium chloride can be used to tune the crystallinity of CH3NH3PbI3 thin film during the deposition for boosting perovskite solar cells (PSCs) device performance.
  • It reacts with organometallic anionic complexes to give the corresponding salts.
  • It can also be used as arylating reagents in Pd-catalyzed Heck reaction.

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This Item
199168218782366188
Tetraphenylphosphonium chloride 98%

Sigma-Aldrich

218790

Tetraphenylphosphonium chloride

Trimethylphenylammonium chloride ≥98%

Sigma-Aldrich

199168

Trimethylphenylammonium chloride

Tetraphenylphosphonium bromide 97%

Sigma-Aldrich

218782

Tetraphenylphosphonium bromide

N-Benzylcinchoninium chloride 98%

Sigma-Aldrich

366188

N-Benzylcinchoninium chloride

assay

98%

assay

≥98%

assay

97%

assay

98%

reaction suitability

core: phosphonium

reaction suitability

core: ammonium

reaction suitability

core: phosphonium

reaction suitability

-

form

solid

form

solid

form

solid

form

solid

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

mp

272-274 °C (lit.)

mp

246-248 °C (dec.) (lit.)

mp

295-300 °C (lit.)

mp

256 °C (dec.) (lit.)

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN0219
BCCJ7071
BCCH5038
BCCF1481
BCCD1266

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Oxoperoxo molybdenum (vi) and tungsten (vi) and oxodiperoxo molybdate (vi) and tungstate (vi) complexes with 8-quinolinol: synthesis, structure and catalytic activity.
Maiti S K, et al.
New. J. Chem., 29(4), 554-563 (2005)
Tetraarylphosphonium Halides as Arylating Reagents in Pd?Catalyzed Heck and Cross?Coupling Reactions.
Hwang L K, et al.
Angewandte Chemie (International Edition in English), 44(38), 6166-6169 (2005)
Efficient Perovskite Solar Cells with Reduced Photocurrent Hysteresis through Tuned Crystallinity of Hybrid Perovskite Thin Films.
Qi J, et al.
ACS Omega, 3(6), 7069-7076 (2018)
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Global Trade Item Number

SKUGTIN
218790-50G04061838775665
218790-5G04061838775672
218790-10G04061838775658