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A26357

Adipic acid

99%

Synonym(s):

Hexanedioic acid

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About This Item

Linear Formula:
HOOC(CH2)4COOH
CAS Number:
Molecular Weight:
146.14
NACRES:
NA.21
PubChem Substance ID:
eCl@ss:
39021711
UNSPSC Code:
12352106
EC Number:
204-673-3
MDL number:
Beilstein/REAXYS Number:
1209788
Assay:
99%
Form:
solid
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vapor density

5 (vs air)

Quality Segment

vapor pressure

1 mmHg ( 159.5 °C)

assay

99%

form

solid

autoignition temp.

788 °F

bp

265 °C/100 mmHg (lit.)

mp

151-154 °C (lit.)

solubility

H2O: soluble 23 g/L at 25 °C

SMILES string

OC(=O)CCCCC(O)=O

InChI

1S/C6H10O4/c7-5(8)3-1-2-4-6(9)10/h1-4H2,(H,7,8)(H,9,10)

InChI key

WNLRTRBMVRJNCN-UHFFFAOYSA-N

General description

Adipic acid is a straight-chain aliphatic dicarboxylic acid, commonly used in the manufacturing of nylon-6,6 and plasticizers. Conventionally it was manufactured from petrochemicals but in recent days it can be synthesized from renewable substrates by means of biological methods.

Application

Adipic acid can be used as a starting material in the preparation of:
  • Aliphatic polyesters by reacting with ethyleneglycol/1,3 propyleneglycol/1,4-butanediol using inorganic acid as a catalyst.
  • Cyclopentanone using a weak base such as Na2CO3.
  • Linear polybutylene adipate (PBA) having carboxylic acids at the terminals by reacting with 1,4-butanediol.


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This Item
1.00090891431012190
assay

99%

assay

-

assay

-

assay

-

solubility

H2O: soluble 23 g/L at 25 °C

solubility

15 g/L

solubility

-

solubility

-

Quality Level

200

Quality Level

500

Quality Level

300

Quality Level

-

bp

265 °C/100 mmHg (lit.)

bp

-

bp

265 °C/100 mmHg (lit.)

bp

265 °C/100 mmHg (lit.)

mp

151-154 °C (lit.)

mp

150.9 °C

mp

151-154 °C (lit.)

mp

151-154 °C (lit.)

form

solid

form

solid

form

-

form

-


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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1

Storage Class

11 - Combustible Solids

flash_point_f

384.8 °F - closed cup

flash_point_c

196 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Ketonic decarboxylation catalysed by weak bases and its application to an optically pure substrate
Renz M and Corma A
European Journal of Organic Chemistry, 2004(9), 2036-2039 (2004)
Biological production of adipic acid from renewable substrates: Current and future methods
Deng Y, et al.
Biochemical Engineering Journal, 105, 16-26 (2016)
Synthesis of aliphatic polyesters by polycondensation using inorganic acid as catalyst
Sokolsky-Papkov M, et al.
Polymers For Advanced Technologies, 22(5), 502-511 (2011)



Global Trade Item Number

SKUGTIN
A26357-100G04061833359440
A26357-1KG04061833359457
A26357-500G04061833359488
A26357-25G04061833359464
A26357-3KG04061833359471

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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