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372439

Sigma-Aldrich

Perfluoro(methyldecalin), mixture of isomers

technical grade, 80%

Sinónimos:

Heptadecafluorodecahydro(trifluoromethyl)naphthalene

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$384.00

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About This Item

Fórmula empírica (notación de Hill):
C11F20
Número de CAS:
51294-16-7
Peso molecular:
512.09
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
24863035
NACRES:
NA.22

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grado

technical grade

Ensayo

80%

Formulario

liquid

índice de refracción

n20/D 1.317 (lit.)

bp

137-160 °C (lit.)

mp

−40 °C (lit.)

densidad

1.95 g/mL at 25 °C (lit.)

cadena SMILES

FC(F)(F)C1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F.FC(F)(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C4(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C34F

InChI

1S/C11F20/c12-1-2(13,6(19,20)10(27,28)9(25,26)4(1,15)16)5(17,18)8(23,24)7(21,22)3(1,14)11(29,30)31

Clave InChI

LWRNQOBXRHWPGE-UHFFFAOYSA-N

Categorías relacionadas

Descripción general

Perfluoro(methyldecalin) is a fluorinated solvent.[1]

Aplicación

Perfluoro(methyldecalin is suitable reagent used to investigate the reactions of iodide anions and anions derived from glow discharge ionization of perfluoro(methyldecalin) with positive ions derived from poly(ethylene glycol).[2] It is suitable reagent used for the oxidation of alcohols with the ruthenium porphyrin at higher temperatures (140ºC) and elevated oxygen pressures (50psi).[1] Perfluoro(methyldecalin (Perfluoro-1-Methyldecalin) may be used in the preparation of undecafluoro-6-trifluoromethyltetralin via defluorination.[3]

Otras notas

Contains perfluorodecalin

Código de clase de almacenamiento

10 - Combustible liquids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

235.0 °F - closed cup

Punto de inflamabilidad (°C)

112.80 °C - closed cup

Equipo de protección personal

Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
MKCR6988
MKCR2138
MKCP2231
MKCL3965
MKCK8963

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Vasily N Korotchenko et al.
Organic & biomolecular chemistry, 6(11), 1961-1965 (2008-05-16)
Carbonylruthenium tetrakis(pentafluorophenyl)porphyrin Ru(TPFPP)(CO) was utilized for the aerobic oxidation of alcohols. The in situ activation of the catalyst with mCPBA provided a species capable of catalyzing the oxidation of alcohols with molecular oxygen. The choice of solvent and additive was
Perfluoro-1-methyldecalin as a potential oxygen carrier with fluid scleral lenses.
M F Refojo et al.
Current eye research, 4(6), 732-733 (1985-06-01)
M K Bakulin et al.
Mikrobiologiia, 75(3), 371-376 (2006-07-29)
The isolates of pseudomonads (56) and of Plesiomonas shigelloides (7) exhibiting ice-forming activity were isolated from plant leaves and rhizosphere. The theoretical possibility of the application of perfluorocarbons (PFC) with a gas-transporting function (perfluorodecalin, carbogal, and perfluoromethyldecalin) for the cultivation
M K Bakulin et al.
Prikladnaia biokhimiia i mikrobiologiia, 43(4), 443-449 (2007-10-13)
The addition of perfluorocarbons (perfluorodecalin, carbogal, and perfluoromethyldecalin) to nitrogen-free liquid media during the submerged cultivation of bacteria of the genus Azotobacter was followed by (1) increases in biomass accumulation and nitrogenase activity and (2) fixation of molecular nitrogen. Addition
D J McIver et al.
Biochimica et biophysica acta, 751(1), 74-80 (1983-03-22)
An effective substitute for pulmonary surfactant must be able to reduce water-vapour surface tensions to under 1 mN/m and it must spread rapidly and spontaneously at the air interface from the aqueous phase. Pure dipalmitoylphosphatidylcholine meets the former requirement, but
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