281042

Tetradecafluorohexane

99%

• Sinónimos: Perfluorohexane
• Fórmula lineal: CF₃(CF₂)₄CF₃
• Número de CAS: 355-42-0
• Peso molecular: 338.04
• Beilstein/REAXYS Number: 1802113
• EC Number: 206-585-0
• MDL number: MFCD00000437
• UNSPSC Code: 12352100
• PubChem Substance ID: 24856965
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: 99%
• form: liquid
• refractive index: n20/D 1.252 (lit.)
• bp: 58-60 °C (lit.)
• mp: -74 °C (lit.)
• density: 1.669 g/mL at 25 °C (lit.)
• functional group: fluoro
• SMILES string: FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
• InChI: 1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20
• InChI key: ZJIJAJXFLBMLCK-UHFFFAOYSA-N

Descripción

General description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium[1].

Application

Tetradecafluorohexane has been used:

• as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution[2]
• to investigate boiling heat transfer mechanisms[3]
• as a photosensitizer in fluorous biphasic singlet oxygenation[4]
• as a novel reaction medium for photooxidation reactions[5]

Información de seguridad

• hcodes: H412
• pcodes: P273 - P501
• Hazard Classifications: Aquatic Chronic 3
• Storage Class: 12 - Non Combustible Liquids
• wgk_germany: WGK 2
• ppe: Eyeshields, Gloves