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540404

Sigma-Aldrich

1,1′-Bis(dimethylsilyl)ferrocene

97%

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About This Item

Empirical Formula (Hill Notation):
C14H22FeSi2
CAS Number:
Molecular Weight:
302.34
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

assay

97%

reaction suitability

core: iron
reagent type: catalyst
reaction type: Olefin Metathesis

refractive index

n20/D 1.564 (lit.)

bp

294-295 °C (lit.)

density

1.007 g/mL at 25 °C (lit.)

SMILES string

[Fe].[H][Si](C)(C)[C]1[CH][CH][CH][CH]1.[H][Si](C)(C)[C]2[CH][CH][CH][CH]2

InChI

1S/2C7H11Si.Fe/c2*1-8(2)7-5-3-4-6-7;/h2*3-6,8H,1-2H3;

InChI key

WAYRNCUBSTTWOE-UHFFFAOYSA-N

Application

  • Catalytic co-initiator in free radical photopolymerization and free radical promoted cationic polymerization reactions

Reactant for:
  • Hydrosilylataion and hydroboration reactions
  • Platinum/nickel catalyzed selective hydrosilylation of alkynes and alkenes
  • Iron-catalyzed dehydrogenative coupling reactions
  • Hydrosilylation and double silylation of carbonyl compounds

pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

122.0 °F - closed cup

flash_point_c

50 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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