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Sigma-Aldrich

Cyclopentadienyl iron(II) dicarbonyl dimer

greener alternative

99%

Synonym(s):

Dicarbonylcyclopentadienyliron dimer, Dicyclopentadienyliron dicarbonyl dimer, Tetracarbonylbis(cyclopentadienyl)diiron, Bis(cyclopentadienyl)tetracarbonyl-diiron, Di(cyclopentadienyl)tetracarbonyl-diiron

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About This Item

Empirical Formula (Hill Notation):
C14H10Fe2O4
CAS Number:
Molecular Weight:
353.92
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

assay

99%

form

solid

reaction suitability

core: iron
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

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mp

194 °C (dec.) (lit.)

greener alternative category

SMILES string

[Fe][Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.4CO.2Fe/c2*1-2-4-5-3-1;4*1-2;;/h2*1-5H;;;;;;

InChI key

DHLWUDJVLCWRGH-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Dinuclear metal carbonyl catalyst for a variety of carbon-carbon bond forming reactions; radical initiator; precursor to alkyland acyliron complexes useful in organic synthesis.

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Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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Davis, R.; Khazal, N. M. S. et al.
Journal of Organometallic Chemistry, 397, 51-51 (1990)
Brookhart, M.; Liu, Y. et al.
Journal of the American Chemical Society, 113, 927-927 (1991)

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