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530980

Sigma-Aldrich

Diphenyliodonium p-toluenesulfonate

electronic grade, ≥99% trace metals basis

Synonym(s):

DPIpTS

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About This Item

Linear Formula:
(C6H5)2IC6H4(SO3)CH3
CAS Number:
Molecular Weight:
452.31
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23

grade

electronic grade

description

Total acid <2 × 10-3 mol/kg
Total base <2 × 10-3 mol/kg

assay

≥99% trace metals basis

mp

188-191 °C (lit.)

solubility

PGMEA: <1%
ethyl lactate: <1%
γ-butyrolactone: ~5%

λmax

222 nm

SMILES string

Cc1ccc(cc1)S([O-])(=O)=O.[I+](c2ccccc2)c3ccccc3

InChI

1S/C12H10I.C7H8O3S/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-6-2-4-7(5-3-6)11(8,9)10/h1-10H;2-5H,1H3,(H,8,9,10)/q+1;/p-1

InChI key

UMIKAXKFQJWKCV-UHFFFAOYSA-M

Application

Cationic photoinitiator. Photoacid generator.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Robin C Anderson et al.
Journal of food protection, 75(4), 758-761 (2012-04-11)
Food producing animals can be reservoirs of Campylobacter, a leading bacterial cause of human foodborne illness. Campylobacter spp. utilize amino acids as major carbon and energy substrates, a process that can be inhibited by thymol and diphenyliodonium chloride (DIC). To
Yi-Na Lin et al.
Sichuan da xue xue bao. Yi xue ban = Journal of Sichuan University. Medical science edition, 40(4), 700-703 (2009-09-22)
To test the effects of two kinds of diaryliodonium on the degree of conversion (DC), the compressive strength (CS) and the cure depth (CD) of the light-curing composite resin. BisS-GMA was used as reisin matrix, with TEGDMA as diluent and
R C Anderson et al.
Journal of applied microbiology, 107(4), 1258-1268 (2009-06-03)
To determine if the purported deaminase inhibitors diphenyliodonium chloride (DIC) and thymol reduce the growth and survivability of Campylobacter. Growth rates of Campylobacter jejuni and Camp. coli were reduced compared to unsupplemented controls during culture in Muellar-Hinton broth supplemented with
Aurélien Bigot et al.
Journal of the American Chemical Society, 133(35), 13778-13781 (2011-08-19)
A new strategy for the catalytic enantioselective α-arylation of N-acyloxazolidinones with chiral copper(II)-bisoxazoline complexes and diaryliodonium salts is described. The mild catalytic conditions are operationally simple, produce valuable synthetic building blocks in excellent yields and enantioselectivities, and can be applied
Susana Castro et al.
Chemical communications (Cambridge, England), 48(72), 9089-9091 (2012-08-03)
A novel metal-free direct arylation of unbiased arenes with diaryliodonium triflates in a process where the use of solvents and additives is not required has been established.

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