726192

Bis(4-methylphenyl)iodonium hexafluorophosphate

98%

• Synonym(s): Bis(p-tolyl)iodonium hexafluorophosphate
• Empirical Formula (Hill Notation): C₁₄H₁₄F₆IP
• CAS Number: 60565-88-0
• Molecular Weight: 454.13
• Beilstein/REAXYS Number: 3581445
• EC Number: 262-301-5
• MDL number: MFCD06656584
• UNSPSC Code: 12352300
• PubChem Substance ID: 329764214
• NACRES: NA.23

Properties

• assay: ≥97.5% (TLC); 98%
• form: solid
• SMILES string: F[P-](F)(F)(F)(F)F.Cc1ccc([I+]c2ccc(C)cc2)cc1
• InChI: 1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1
• InChI key: LHLVGWWCRPPKBC-UHFFFAOYSA-N

Description

General description

Bis(4-methylphenyl)iodonium hexafluorophosphate is a white powder. It melts at 175-180 °C and shows an UV absorption peak at 267nm. 1

Application

• Covalent Functionalisation of Few-Layer Black Phosphorus using Aryl Iodonium Salts and Comparison to Diazonium Modified Black Phosphorus: Explores the functionalization of black phosphorus using bis(4-methylphenyl)iodonium hexafluorophosphate and compares it to diazonium modification (M Van Druenen, 2019).


• Iodonium sulfonates as high‐performance coinitiators and additives for CQ‐based systems: Toward aromatic amine‐free photoinitiating systems: Examines the effectiveness of iodonium sulfonates and bis(4-methylphenyl)iodonium hexafluorophosphate in CQ-based photoinitiating systems (J Kirschner et al., 2019).


• Thiophene-substituted phenothiazine-based photosensitisers for radical and cationic photopolymerization reactions under visible laser beams (405 and 455 nm): Studies the use of thiophene-substituted phenothiazine in combination with bis(4-methylphenyl)iodonium hexafluorophosphate for effective photopolymerization (P Chao et al., 2016).

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P280 - P305 + P351 + P338 - P310
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable