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460702

Sigma-Aldrich

Titanium(III) chloride tetrahydrofuran complex (1:3)

97%

Synonym(s):

THF-titanium trichloride complex, (3:1), Titanium trichloride tetrahydrofuran complex (1:3), Titanium trichloride tri(THF), Titanium trichloride tris(tetrahydrofuran), Trichlorotris(THF)titanium, Trichlorotris(tetrahydrofuran)titanium

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About This Item

Empirical Formula (Hill Notation):
C12H24Cl3O3Ti
CAS Number:
Molecular Weight:
370.54
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:

assay

97%

form

solid

reaction suitability

reagent type: catalyst
core: titanium

mp

>250 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Ti](Cl)Cl.C1CCOC1.C2CCOC2.C3CCOC3

InChI

1S/3C4H8O.3ClH.Ti/c3*1-2-4-5-3-1;;;;/h3*1-4H2;3*1H;/q;;;;;;+3/p-3

InChI key

MIDYWIPTCYRMQF-UHFFFAOYSA-K

Features and Benefits

Used for the synthesis of bimetallic titanium(III) complexes with a triple-helix structure.

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Rele, S.; Talukdar, S.; Banerji, A.
Tetrahedron Letters, 40, 767-767 (1999)
Talukdar, S.; Banerji, A.
The Journal of Organic Chemistry, 63, 3468-3468 (1998)

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