432245

Dichlorotetrakis(triphenylphosphine)ruthenium(II)

• Linear Formula: [(C₆H₅)₃P]₄RuCl₂
• CAS Number: 15555-77-8
• Molecular Weight: 1225.15
• MDL number: MFCD09039275
• UNSPSC Code: 12161600
• PubChem Substance ID: 24867082
• NACRES: NA.22

Properties

• reaction suitability: core: ruthenium; reagent type: catalyst
• SMILES string: Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
• InChI: 1S/4C18H15P.2ClH.Ru/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h4*1-15H;2*1H;/q;;;;;;+2/p-2
• InChI key: OIWNHEPSSHYXTG-UHFFFAOYSA-L

Description

Application

Catalyst for:

• Selective hydrogenation of maleic anhydride or succinic anhydride
• Sythesis of portions of the natural antibiotic tetrodecamycin
• Oxidation of hydroxamic acid
• Hydroesterification reactions
• Hydroboration of alkenes
• Oxidation of sulfide

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332
• pcodes: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves