The saga of rhodium (III) nitrate complexes and their speciation in solution: An integrated experimental and quantum chemical study of rhodium(III) nitrate complexes in solution (SN Vorobyeva et al., 2022).
Angewandte Chemie (International ed. in English), 54(46), 13715-13718 (2015-09-18)
A new type of intermolecular rhodium(II)-catalyzed [5+3] cycloaddition has been developed. This higher-order cycloaddition between pyridinium zwitterion 1,5-dipole equivalents and enol diazoacetates enables the formation of eight-membered heterocyclic skeletons, which are otherwise difficult to construct. The optimized cycloaddition occurs efficiently under
Journal of hazardous materials, 298, 282-293 (2015-06-16)
Although asbestos represents today one of the most harmful contaminant on Earth, in 72% of the countries worldwide only amphiboles are banned while controlled use of chrysotile is allowed. Uncertainty on the potential toxicity of chrysotile is due to the
Angewandte Chemie (International ed. in English), 53(48), 13083-13087 (2014-10-01)
A regio-, diastereo-, and enantioselective [4+3] cycloaddition between vinylcarbenes and dienes has been achieved using the dirhodium tetracarboxylate catalyst [Rh2(S-BTPCP)4]. This methodology provides facile access to 1,4-cycloheptadienes that are regioisomers of those formed from the tandem cyclopropanation/Cope rearrangement reaction of
Large area x-ray imagers based on complementary metal-oxide-semiconductor (CMOS) active pixel sensor (APS) technology have been proposed for various medical imaging applications including digital breast tomosynthesis (DBT). The low electronic noise (50-300 e-) of CMOS APS x-ray imagers provides a
Journal of trace elements in medicine and biology : organ of the Society for Minerals and Trace Elements (GMS), 29, 130-135 (2014-07-24)
Although a number of studies have measured circulating levels of some trace elements in preeclampsia (PE) and compared to healthy pregnant (HP), there is no consensus yet about the deficiency of some metals and development of hypertensive disorders in pregnancy.
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